通过对铁离子在非晶态固体中的配位体和配位数的变化以及铁与其它离子的极化作用等进行研究,分析了玻璃网络形成体、网络变性体、铁离子价态和浓度以及工艺因素等对铁离子在非晶态固体中呈色性能的影响。为今后进一步开发铁离子着色的高级色釉及颜色玻璃新品种奠定一定的物理化学基础。
Through the study of ligand and ligancy(coordination number) of Fe ion in amorphous solid and the polarized action between Fe ion and other ions,the effects on glaze color were analyzed including the kinds of network formers,network modifier category and its concentration,the valence state of Fe and the change of its concentration.The study lays the physical and chemical foundation for the further exploitation of Fe ion coloring ceramic glaze and glass.