用丁腈橡胶(NBR)作基体,分别研究了在NBR中原位生成丙烯酸锂(LiAA)及在NBR/LiAA中添加氯化镧(LaCl3)后,硫化胶体系电学性能的变化。结果表明,在NBR中原位生成LiAA,可降低NBR的体积电阻率。使其由绝缘材料转变为抗静电材料;进一步在NBR/LiAA中添加LaCl3。体系体积电阻率继续降低,在LaCl3用量为20份左右时,体系体积电阻率有一最低值并趋于稳定。
The in situ preparation of lithium acrylate (LiAA) in nitrile rubber (NBR) and the effect of lanthanum acrylate (LaCl3) on the electrical resistivity of NBR/LiAA composites were investigated. The results indicated that the in situ prepared LiAA could decrease the volume electrical resistivity and changed the composites from insulated to antistatic; the volume electrical resistivity continued to decrease after LaCl3 was added to NBR/LiAA composites. The volume electrical resistivity reached the minimum when about 20 phr LaCl3 was added.