中文摘要：

采用水热方法合成出一种新型配位聚合物[Cu（Ox）（4，4＇-bpy）]n（ox=草酸根离子，4，4＇-bpY =4，4＇-联吡啶），并通过X射线单晶结构分析、元素分析以及红外光谱测定对该化合物进行了表征．结果表明，标题化合物属于单斜晶系，Cm空间群，晶胞参数α=1.1921（7）nm，b=1.153（7）nm，C=0.5155（4）nm，β=113.38（3）°，V=0.6291（7）nm^3，Z=2．该化合物是一个由{Cu（OX）}。链通过桥联配体4，4＇-bpy垂直相连并具有矩形格子结构的二维层状配位聚合物，层与层之问交错排列，通过C4，4＇-bpy…Oox层间氢键作用，进一步扩展成三维超分子网络结构。

英文摘要：

A new polymer [Cu（ox）（4,4＇-bpy） ]n（1）（ox=C20^2-4, 4,4＇-bpy = 4,4＇-bipyridine） was hydro- thermally synthesized and characterized via elemental analyses, IR spectrum and single crystal X-ray diffrac-tion. The polymer crystallizes in a monoelinie system, space group Cm,α=1.1921（7）nm, b=1.153（7）nm, c=0.5155（4）nm,β=113.38（3）°, V=0.6291（7）nm^3, Z=2. Cu atom in the title compound is in an oetahedral geometry with four O atoms from two bis-ehelating oxalate ligands in equatorial plane and two N atoms from the 4,4＇-bpy ligands in the axial position. The crystal structure possesses infinite {Cu（ox）}n chains connected with each other by the bridging 4,4＇-bpy ligands in a perpendicular manner, leading to a 2D layered network with rectangular grids. The layers stacking in a staggered fashion are further assembled by C4.4,.bpy H…Oox hydrogen bonds and lead to a 3D supramoleeular architecture.