欢迎您！东篱公司
退出
-
申报数据库
-
立项数据库
-
成果数据库
-
项目获奖数据库
中文摘要：
合成并表征了一种胆固醇的直链葡萄糖衍生物（1），考察了其在36种常见溶剂中的胶凝行为．结果表明：1可使11种溶剂胶凝；1／氯仿体系可以室温成胶；多个体系的溶胶-凝胶相转变温度（Tgel）可超过相应溶剂的沸点，此外，对干凝胶形貌的显微分析发现，胶凝剂1的聚集方式呈现出糖类胶凝剂所具有的纤维网状结构特征，FTIR和H NMR研究表明，除了胆固醇的范德华堆积之外，氢键作用也是该化合物成胶的重要驱动力。
英文摘要：
A new linear-glucose-appended cholesterol derivative （1） has been synthesized and characterized, and its gelation ability was evaluated in 36 solvents. 1 was found to gelate 11 of the solvents tested. More importantly, it gels chloroform at room temperature. Furthermore, for a number of the gel systems, their sol-gel phase-transition temperarares （ Tgel） are higher than the boiling points of their corresponding solvents. SEM observation shows that the representative xerogels are characterized by fibrous network structures. FHR and H NMR measurements reveal that hydrogen-bonding interaction between the gelator molecules is one of the main driving forces for the formation of the gels.
同期刊论文项目
同项目期刊论文
A Novel Two-Component Physical Gel Based on Interaction Between Poly(Acrylic Acid) and 6-Deoxy-6-Ami
Computer Simulation Study on The Structural-Optical Related Properties of a Pyrene-Functionalized Fl
Novel Dimeric Cholesteryl-Based A(LS)2 Low-Molecular-Mass Gelators with a Benzene Ring in The Linker
Glucose-Based Fluorescent Low-Molecular Mass Compounds: Creation of Simple and Versatile Supramolecu
A dansyl-based fluorescent film: Preparation and sensitive detection of nitroaromatics in aqueous ph
Preparation of monolayer-assembled fluorescent film and its sensing performances to hidden nitroarom
A novel low-molecular-mass gelator with a redox active ferrocenyl group: Tuning gel formation by oxi
New dicholesteryl-based gelators: gelling ability and selective gelation of organic solvents from th
Fluorescent Film Sensor for Vapor-Phase Nitroaromatic Explosives via Monolayer Assembly of Oligo(dip
A novel picric acid film sensor via combination of the surface enrichment effect of chitosan films a
Monomolecular-layer assembly of oligothiophene on glass wafer surface and its fluorescence sensitiza
期刊信息
位置：