与液体电解质相比较,聚合物电解质以其易加工、设计灵活、质量轻、安全无毒的特点而受到人们的广泛关注,具有取代液态电解质的潜在应用价值,而超支化/星形聚合物以其无定形、低玻璃化转变温度、支化结构等特点可被用于固态电解质。本文综述了超支化/星形聚合物电解质材料的研究进展,重点介绍了超支化/星形聚合物基电解质和超支化/星形聚合物共混基电解质,并对超支化/星形聚合物单一离子导体在锂离子电池方面的应用前景作了概述。
Compared with liquid electrolyte, polymer electrolyte has widely attracted researchers' attention, and has the potential to replace organic liquid electrolyte because of the advantages such as easy processing, flexible design, light weight, safety and non-toxicity. Hyperbranched/star polymer with amorphousness, low glass transition temperature and unique topology has been studied as solid polymer electrolyte. In this review, research progress in hyperbranched/star polymer electrolyte is presented. Special interests are focused on the hyperbranched/star polymer-based electrolytes, hyperbranched/star polymer blend-based electrolyte. Besides, the application of hyperbranched/star polymer based single ion electrolyte for lithium ion battery is also prospected.