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中文摘要：
整体柱作为新一代色谱固定相,具有原位制备、快速传质和高通透性的特点,近年来引起人们的极大关注。智能型聚合物作为一类功能性材料,能在温度、pH和盐等环境因素的刺激下产生特异性响应变化,通常被修饰到固相载体表面用来构造环境敏感性材料,使得该智能材料在药物控释、化学传感和细胞生长等领域有着广泛的应用。因此,在整体柱上构造智能型表面更为其在色谱领域的发展提供了新的契机。本文主要综述了近年来智能型整体柱在色谱领域的研究进展。
英文摘要：
In recent years,great attention has been paid to monolith,which is developed as a new generation of chromatographic stationary phase,due to its advantages of in-situ preparation,fast mass transfer and high permeability.Besides,as a class of functional materials,intelligent polymer could response to external environmental stimuli,such as temperature,pH,salt and so on.This intelligent polymer is usually modified onto solid support surface for fabrication of environmental responsive materials,which could be widely applied in drug release,chemical sensing,cell growth,etc.As a result,the construction of intelligent surface on monolith can provide new opportunities for its development in chromatography.This review summarizes the development of intelligent monolith as chromatographic stationary phase during recent years.
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Macroporous polymer monoliths with a well-defined three dimensional skeletal morphology derived from
Fabrication of nylon membrane-based microfluidic chips and its application in color sensing of gluco
Facile Fabrication of Polymeric Ionic Liquid Grafted Porous Polymer Monolith for Mixed-Mode High Per
Thermoresponsive Oligo(ethylene glycol)-Based Polymer Brushes on Polymer Monolith for All-Aqueous Ch
Facile preparation of surface-exchangeable core@shell iron oxide@gold nanoparticles for magnetic sol
Preparation of a novel polymer monolith with functional polymer brushes by two-step atom transfer ra
One-pot synthesis of tyrosine-stabilized fluorescent gold nanoclusters and its application as turn-o
Determination of preservatives in soft drinks by capillary electrophoresis with ionic liquids as the
A new chiral ligand exchange capillary electrophoresis system based on Zn(II)-L-leucine complexes co
Poly(2-vinyl-4,4-dimethylazlactone-functionalized magnetic nanoparticles as carriers for enzyme immo
Influence of ionic liquids as electrolyte additives on chiral separation of dansylated amino acids b
The facile fabrication of polymeric ionic liquid grafted porous polymer monolith for mixed-mode high
Development of new chiral ligand exchange capillary electrophoresis system with amino acid ionic liq
Development of a capillary electrophoresis system withMn(II) complexes and β-cyclodextrin as the dua
A well-defined block copolymer serving as surfactants in separation of 1, 4-dihydropyridines by open
Assay of vitamin B in urine by capillary electrochromatography with methacrylate-based monolithic co
Parallel comparative studies on the toxic effects of unmodified CdTe quantum dots, gold nanoparticle
A spectroscopic off-on probe for simple and sensitive detection of carboxylesterase activity and its
A novel chiral ligand exchange capillary electrophoresis system with amino acid ionic liquid as liga
Imaging Different Interactions of Mercury and Silver with Live Cells by a Designed Fluorescence Prob
A simple and sensitive method for visual detection of phosgene based on the aggregation of gold nano
Magnetically separable Fe3O4-Ag3PO4 sub-micrometre composite: facile synthesis, high visible light-d
7-((5-Nitrothiophen-2-yl)methoxy)-3H-phenoxazin-3-one as a spectroscopic off-on probe for highly sen
Charge-transfer interaction between melamine and quinones: Towards voltammetric determination of mel
In situ formation of three-dimensional and uniform Pt/Carbon nanotube nanocomposites from ionic liqu
Microchip CE-LIF method for the hydrolysis of L-glutamine by using L-asparaginase enzyme reactor bas
Cysteine-modulated colorimetric sensing of extracellular Mg2+ in rat brain based on the strong chela
Real-time colorimetric assay of inorganic pyrophosphatase activity based on reversibly competitive c
ZeoliticImidazolate framework-based electrochemical biosensor for in vivo electrochemical measuremen
Microfluidic chip-based online electrochemical detecting system for continuous and simultaneous moni
Photodecomposition of Ferrocenedicarboxylic Acid in Methanol to Form an Electroactive Infinite Coord
Folic acid-functionalized fluorescent gold nanoclusters with polymers as linkers for cancer cell ima
Hybridization of Bioelectrochemically Functional Infinite Coordination Polymer Nanoparticles with Ca
Immobilization of trypsin via reactive polymer grafting from magnetic nanoparticles for microwave-as
Competitive Coordination of Cu2+ between Cysteine and Pyrophosphate Ion: Toward Sensitive and Select
Bioelectrochemically Active Infinite Coordination Polymer Nanoparticles: One-Pot Synthesis and Biose
Sensitive and selective voltammetric measurement of Hg2+ by rational covalent functionalization of g
Study on the decrease of renal D-amino acid oxidase activity in the rat after renal ischemia by chir
A graphene oxide-peptide fluorescence sensor tailor-made for simple and sensitive detection of matri
Rhodamine B Piperazinoacetohydrazine: A Water-Soluble Spectroscopic Reagent for Pyruvic Acid Labelin
Use of a rhodamine-based bifunctional probe in N-terminal specific labeling of Thermomyces lanuginos
A highly specific ferrocene-based fluorescent probe for hypochlorous acid and its application to cel
Determination of sodium benzoate by chiral ligand exchange CE based on its inhibitory activity in D-
Online Electrochemical Measurements of Ca2+ and Mg2+ in Rat Brain Based on Divalent Cation Enhanceme
A non-oxidative electrochemical approach to online measurements of dopamine release through laccase-
Potential-controllable green synthesis and deposition of metal nanoparticles with electrochemical me
Spectroscopic Response of Ferrocene Derivatives Bearing a BODIPY Moiety to Water: A New Dissociation
An unprecedented strategy for selective and sensitive fluorescence detection of nitric oxide based o
A new resorufin-based spectroscopic probe for simple and sensitive detection of benzoyl peroxide via
Reactive polymer as a versatile toolbox for construction of multifunctional superparamagnetic nanoco
Amphiphilic block copolymer modified magnetic nanoparticles for microwave-assisted extraction of pol
A versatile method for the preparation of polyacrylamide derivative functionalized thermo-responsive
Preparation of poly(N-isopropylacrylamide)-grafted well-controlled 3D skeletal monolith based on E-5
A colorimetric sensor for determination of cysteine by carboxymethyl cellulose-functionalized gold n
A chiral ligand exchange CE essay with zinc(II)-L-valine complex for determining enzyme kinetic cons
Distinguishing Folate-Receptor-Positive Cells from Folate-Receptor-Negative Cells Using a Fluorescen
Fluorescence sensing of adenosine deaminase based on adenosine induced self-assembly of aptamer stru
Nitroreductase Detection and Hypoxic Tumor Cell Imaging by a Designed Sensitive and Selective Fluore
Alkaline Post-Treatment of Cd(II)-Glutathione Coordination Polymers: Toward Green Synthesis of Water
Facile one-pot synthesis of L-proline-stabilized fluorescent gold nanoclusters and its application a
Monolith and coating enzymatic microreactors of L-asparaginase: kinetics study by MCE-LIF for potent
In vivo electrochemical monitoring of the change of cochlear perilymph ascorbate during salicylate-i
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