DL-1为东北大学新研制的阴离子反浮选捕收剂,为了检验其性能及效果,以齐大山铁矿选矿厂铁品位为46.02%的混磁精为试样进行了反浮选试验,并借助Zeta电位检测和红外光谱分析手段对DL-1反浮选石英的机理进行了探讨.结果表明:①以DL-1为捕收剂,采用1粗1扫、中矿返回闭路流程常温反浮选试验试样,获得了铁品位为65.38%、铁回收率为89.56%的铁精矿;DL-1对温度变化的适应能力较强,且可在CaCl2用量较低的情况下高效捕收试样中的石英.②在pH =9~ 12的碱性水溶液中,石英与DL-1间存在静电斥力,CaCl2对石英活化后可大大削弱这种静电斥力;在pH =9~ 11.45的矿浆中,被Ca2+活化的石英与DL-1间既可能发生静电吸附也可能发生化学吸附,而在pH> 11.45的矿浆中,被Ca2活化的石英对DL-1有强烈的静电吸引,因而比在pH=9 ~11.45区间可以更好地完成对石英的吸附和捕收.③在pH=11.50时,DL-1与石英表面同时存在物理吸附、氢键及化学吸附,因而DL-1对无Ca2活化的石英也有很好的捕收效果.
DL-1 is a newly anionic reverse flotation collector developed by Northeastern University.In order to test the floating properties,mixed magnetic concentrate from Qidashan Dressing Plant with Fe grade of 46.02% was used to make reverse flotation tests,and the mechanism in quartz reverse flotation by DL-1 is discussed with Zeta potential measurement and infrared spectrum analysis.The results showed that:①Iron concentrate with Fe grade of 65.38%,recovery of 89.56% was obtained through closed-circuit reverse flotation flowsheet of one roughing,one scavenging,and middles back to the flowsheet in turn with normal temperature and DL-1 as collector; DL-1 can endure temperature changes,and high efficiently collecting quartz at a lower dosage of CaC12.②There are electrostatic repulsion between quartz and DL-1 with pH of 9 ~ 12 in aqueous alkaline solution,and can be weakened by activation of CaCl2 to quartz; electrostatic/chemical adsorption may occur between quartz activated by Ca2+ and DL-1 with pH of 9 ~ 11.45,there are strong electrostatic attraction of quartz activated by Ca2+ to DL-1 with pH > 11.45,therefore DL-1 can well adsorb and collect quartz at pH range of 9 ~ 11.45.③There are physical adsorption,hydrogen bond and chemical adsorption coexist between DL-1 and quartz surface with pH of 11.45,DL-1 can also well collect quartz without Ca2+ activation.