采用高温固相法在800℃下制备出系列白色长余辉荧光粉Sr3Al2O5Cl2∶Eu^2+,Tm^3+,并研究了它们的结构、形貌及发光性能。样品Sr2.91Al2O5Cl2∶0.04Eu^2+,0.05 Tm^3+具有单一晶相和纳米纤维结构。该样品在紫外光激发下表现出两个很强的宽带发射(分别位于^448 nm和^590 nm)。它的余辉寿命大约是20 min。利用此种荧光粉所制作出的白光LED器件表现出很强的白光发射。
White long persistent phosphors, Sr3Al2O5Cl2: Eu2+ ,Tm3+ , have been successfully prepared by the solid state reaction at 800 ℃. The as-prepared sample Sr2.91Al2O5Cl2:0.04Eu2+ , 0.05 Tm3+ shares single phase and regular nano-fi- her morphology. This sample exhibits two broad emission bands located at - 448 nm and - 590 nm, respectively, and its white persistent duration is about 20 min ( 〉 0.35 mcd/m2 ). At last, intense white light can be found from the white light-emitting diode with Sr2.91Al2 O5 Cl2: 0.04Eu2 + , 0. 05 Tm3 +.