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活性炭涂层电极电吸附除盐性能研究
  • ISSN号:1009-6094
  • 期刊名称:安全与环境学报
  • 时间:2012
  • 页码:28-32
  • 分类:X506[环境科学与工程—环境工程]
  • 作者机构:[1]东北大学资源与土木工程学院,沈阳110819
  • 相关基金:国家自然科学基金项目(51178088)
  • 相关项目:铝/铁双电极周期换向电凝聚处理废水的机理研究
中文摘要:

构造了简易的电容去离子(CDI)反应装置,以活性炭粉末为吸附材料,聚偏氟乙烯(PVDF)为黏结剂,石墨粉为导电剂。这3种物质的质量比为8∶1∶1。采用涂覆分解法制备活性炭电极,研究其电吸附除盐性能。利用扫描电子显微镜(SEM)对电极的表观形态进行分析,利用电化学工作站对电极材料的电化学性能进行分析,并估算单位质量电极的电容。通过单因素试验得到电容去离子试验的最佳反应条件:端电压为1.6 V,流量为10 L/min,极板间距为2 mm。此条件下离子去除率可达47.9%。吸附达平衡后断开电源,进行电极可再生性研究。结果表明,电极在短时间内即可再生。

英文摘要:

The present paper would like to introduce a renovated electro-absorptive desalination method by using activated carbon coating electrodes.Since it is of great importance to remove ion from aqueous solutions both in natural environment and in industrial processes,for example,the desalination of seawater,there has been existing a promising method commonly known as capacitive deionization(CDI) for saline ion removal.It is just for satisfying such a need,we have developed a simplistic CDI cell reactor which we name flowing-through-capacitor(FTC) to study the mechanism of the electrosorptive desalination.In our work,we have prepared some activated carbon-coating electrodes in a simple and economic manner by coating a slurry mixture made of activated carbon powder(ACP) in a polymer solution including binder poly vinylidene fluoride(PVDF) and conductive graphite powder dissolved in di-methylacetamide(DMAc) on the current collector(a graphite plate).And,then,the mixture and the electric current collector were let to dry at 60 in a vacuum stove,in which the electrodes could be made to turn into activated carbon powder with a ratio of PVDF: graphite powder in 8:1:1.The electrodes here prepared can be characterized by using Scanning Electronic Microscopy(SEM) and Electrochemical workstation to analyze their surface morphology and electrochemical performance.The results of the SEM indicate that the activated carbon powder and PVDF binders tend to be effectively bonded.Measuring the cyclic voltammetry(CV) through a three-electrode-system in the CHI660 electrochemical workstation,we can obtain the specific capacitance from CV was 59.2 F/g.And,as a result,we can find that the influential factors of the electrodes chosen may have bias potential with their flowing rate and the distance between them.The best reaction conditions obtained by optimizing the affecting factors can be shown as follows: the bias potential was 1.6 V,the flowing rate was 10 L/min,the distance between the two electrod

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期刊信息
  • 《安全与环境学报》
  • 北大核心期刊(2011版)
  • 主管单位:中国兵器工业集团公司
  • 主办单位:北京理工大学 中国环境科学学会 中国职业安全健康协会
  • 主编:冯长根
  • 地址:北京市海淀区中关村南大街5号
  • 邮编:100081
  • 邮箱:aqyhjxb@263.net;aqyhjxb@wuma.com.cn
  • 电话:010-68913997
  • 国际标准刊号:ISSN:1009-6094
  • 国内统一刊号:ISSN:11-4537/X
  • 邮发代号:2-770
  • 获奖情况:
  • 获首届《CAJ-CD》执行优秀期刊奖,中国科技论文统计源期刊
  • 国内外数据库收录:
  • 美国化学文摘(网络版),中国中国科技核心期刊,中国北大核心期刊(2008版),中国北大核心期刊(2011版),中国北大核心期刊(2014版)
  • 被引量:17182