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水电解槽制氢装置冷却系统故障浅析
  • ISSN号:1000-5900
  • 期刊名称:《湘潭大学自然科学学报》
  • 时间:0
  • 分类:TF125.24[冶金工程—粉末冶金;冶金工程—冶金物理化学]
  • 作者机构:[1]中南大学粉末冶金国家重点实验室,长沙410083
  • 相关基金:国家973计划资助项目(2003CB615707);国家自然科学基金项目(20476106)
中文摘要:

以Ti、Al混合粉末为原料,通过反应烧结制备TiAl金属间化合物多孔过滤材料,分析压制压力对孔隙率、最大孔径及渗透系数的影响。结果表明:随着压制压力从90MPa增加到375MPa时,总孔隙率呈“急剧减小-平缓减小-平缓减小-平缓减小”的变化趋势,开孔隙率呈“急剧减小-平缓减小-显著增大-急剧减小”的变化趋势,最大孔径呈“急剧减小-减小-减小-减小”变化,而渗透系数呈“急剧减小-平缓减小-平缓增大-急剧减小”的变化。综合考虑压制压力对孔隙率、最大孔径及渗透系数的影响,当压制压力为250MPa时,TiAl合金烧结坯具有较大的开孔隙率、较小的孔径和较大的渗透系数。改变颗粒之间的间隙大小及数量,从而影响反应造孔和孔隙长大,是压制压力影响孔隙率、最大孔径的机制。

英文摘要:

A porous TiAl intermetallics is fabricated using Ti and Al elemental powder by reactive sintering process, and the relationships between pressing pressure and porosity, maximum size as well as permeability coefficient are analysed. The results can be summarized as follows: under experiment condition, when pressing pressures lie in 90 MPa~375 MPa, varying trend of overall porousity is "rapidly decrease-gently decrease-gently decrease-gently decrease", varying trend of the open porousity is "rapidly decrease- gently decrease-increase-decrease", varying trend of maximum size is "rapidly decrease-decrease- decrease-decrease", and varying trend of permeability coefficient is "rapidly decrease-gently decrease- gently increase- rapidly decrease". The relationships between pressing pressure and porosity, maximum size as well as permeability coefficient are comprehensively considered, the sintered specimens of TiAl alloy has a rather large open porousity, smaller pore size and a rather large permeability coefficient when pressing pressure lies in 250 MPa. It is the acting mechanism of pressing pressure that numbers of mesopore, reactive pole and growing nucleus of aperture are changed.

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期刊信息
  • 《湘潭大学自然科学学报》
  • 北大核心期刊(2011版)
  • 主管单位:湖南省教育厅
  • 主办单位:湘潭大学
  • 主编:黄云清
  • 地址:湖南湘潭市
  • 邮编:411105
  • 邮箱:jxtus@xtu.edu.cn
  • 电话:0731-58292143
  • 国际标准刊号:ISSN:1000-5900
  • 国内统一刊号:ISSN:43-1066/N
  • 邮发代号:42-33
  • 获奖情况:
  • 全国优秀科技期刊,湖南省一级期刊
  • 国内外数据库收录:
  • 俄罗斯文摘杂志,美国化学文摘(网络版),美国数学评论(网络版),德国数学文摘,荷兰文摘与引文数据库,中国中国科技核心期刊,中国北大核心期刊(2004版),中国北大核心期刊(2008版),中国北大核心期刊(2011版),中国北大核心期刊(2014版)
  • 被引量:4425