标题化合物C21H15N3是由苯甲醛、2-乙酰基吡啶和醋酸铵在水相中经微波辐射反应而得,反应在24min内完成.结构通过单晶x射线衍射法测定,其晶体属正交晶系,空间群Pbcn,a=1.227(4),b=1.197(4),c=1.110(3)nm,V=1.630(9)nm^3,Mr=309.36,Z=4,Dc=1.260g/cm^3,λ=0.071073nm,,μ(MoKa)=O.076mm^-1,F(000)=648,R=0.0398,Rω=0.0928.
The title compound (C21 H15 N3 ) was synthesized by the one-pot reaction of benzaldehyde, 2-acetylpyridine and ammonium acetate under microwave irradiation without catalyst and its crystal structure was determined by single-crystal X-ray diffraction. The crystal is of orthorhombic, space group Pbcn with a=1. 227(4), b=1. 197(4), c=1. 110(3) nm, V=1. 630(9) nm^3, Mr= 309.36, Z=4, Dc=1. 260 g/cm^3, λ=0.071 073 nm, μ(Mo Ko)=0.076 mm^-1, F(000)=648, R= 0. 039 8, Rω=0. 092 8.