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响应曲面法优化XG/AM接枝共聚物的合成工艺
  • ISSN号:1004-2849
  • 期刊名称:《中国胶粘剂》
  • 时间:0
  • 分类:TQ432.2[化学工程]
  • 作者机构:[1]教育部轻化工助剂化学与技术重点实验室,陕西科技大学化学与化工学院,陕西西安710021
  • 相关基金:国家自然科学基金资助项目(50573046); 陕西科技大学研究生创新基金资助项目
中文摘要:

为优化黄原胶(XG)与丙烯酰胺(AM)接枝共聚物(XG-g-AM)的合成工艺,以产品接枝率、接枝效率的回归综合得分为指标,采用响应曲面(RS)法分析了m(AM)∶m(XG)比例、XG浓度和辐射总剂量(60Co-γ为辐射源)对产物接枝参数的影响,并建立了相应的预测模型;同时利用元素分析、红外光谱(FT-IR)和X射线衍射(XRD)法对接枝产物的结构进行了表征。结果表明:AM已成功接枝在XG上,并且当m(AM)∶m(XG)=2.9∶1、XG浓度为9.8 g/L和辐射总剂量为5.9 kGy时,相应产品的接枝率、接枝效率回归综合得分的预测值(19.95)最大;验证了最佳工艺条件下制备的产品接枝率为130.2%,平均接枝效率为80.4%,综合得分为19.78,试验值与预测值吻合较好,说明该模型可以较好地反映综合得分与各影响因素之间的关系。

英文摘要:

In order to optimize technology of preparing XG(xanthan gum)-g-AM(acrylamide)(namely graft copolymer between XG and AM),the influences of some factors(such as mass ratio of AM to XG,concentration of XG,total radiation dose with 60Co-γ as radiation source) were analysed on graft parameters of XG-g-AM by response surface(RS) method with regressive synthesis score of grafting ratio and grafting efficiency as evaluation indexes.The relevant forecast model was established.The structures of XG-g-AM were characterized by element analysis,FT-IR and XRD methods.The results showed that the AM was successfully grafted onto XG,and the relevant XG-g-AM product had maximum forecast value(19.95) of regressive synthesis score of grafting ratio and grafting efficiency when mass ratio of m(AM)∶m(XG) was 2.9∶1,concentration of XG was 9.8 g/L and total radiation dose was 5.9 kGy.It was validated that the experiment value and forecast value were approximate because the grafting ratio and average grafting efficiency were 130.2% and 80.4% respectively,and synthesis score was 19.78 for XG-g-AM prepared by optimal process conditions.So the forecast model can preferably describe the relation between synthesis score and various influence factors.

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期刊信息
  • 《中国胶粘剂》
  • 中国科技核心期刊
  • 主管单位:上海华谊(集团)公司
  • 主办单位:上海市合成树脂研究所 中国胶粘剂工业协会 全国粘合剂信息站
  • 主编:刘芳
  • 地址:上海市詛路西路1251号
  • 邮编:201702
  • 邮箱:gxlj@chinajournal.net.cn
  • 电话:021-64821610
  • 国际标准刊号:ISSN:1004-2849
  • 国内统一刊号:ISSN:31-1601/TQ
  • 邮发代号:4-454
  • 获奖情况:
  • 华东地区优秀科技期刊(2012年)、上海市科技期刊...
  • 国内外数据库收录:
  • 美国化学文摘(网络版),中国中国科技核心期刊,中国北大核心期刊(2008版),中国北大核心期刊(2011版),中国北大核心期刊(2014版)
  • 被引量:7974