为优化黄原胶(XG)与丙烯酰胺(AM)接枝共聚物(XG-g-AM)的合成工艺,以产品接枝率、接枝效率的回归综合得分为指标,采用响应曲面(RS)法分析了m(AM)∶m(XG)比例、XG浓度和辐射总剂量(60Co-γ为辐射源)对产物接枝参数的影响,并建立了相应的预测模型;同时利用元素分析、红外光谱(FT-IR)和X射线衍射(XRD)法对接枝产物的结构进行了表征。结果表明:AM已成功接枝在XG上,并且当m(AM)∶m(XG)=2.9∶1、XG浓度为9.8 g/L和辐射总剂量为5.9 kGy时,相应产品的接枝率、接枝效率回归综合得分的预测值(19.95)最大;验证了最佳工艺条件下制备的产品接枝率为130.2%,平均接枝效率为80.4%,综合得分为19.78,试验值与预测值吻合较好,说明该模型可以较好地反映综合得分与各影响因素之间的关系。
In order to optimize technology of preparing XG(xanthan gum)-g-AM(acrylamide)(namely graft copolymer between XG and AM),the influences of some factors(such as mass ratio of AM to XG,concentration of XG,total radiation dose with 60Co-γ as radiation source) were analysed on graft parameters of XG-g-AM by response surface(RS) method with regressive synthesis score of grafting ratio and grafting efficiency as evaluation indexes.The relevant forecast model was established.The structures of XG-g-AM were characterized by element analysis,FT-IR and XRD methods.The results showed that the AM was successfully grafted onto XG,and the relevant XG-g-AM product had maximum forecast value(19.95) of regressive synthesis score of grafting ratio and grafting efficiency when mass ratio of m(AM)∶m(XG) was 2.9∶1,concentration of XG was 9.8 g/L and total radiation dose was 5.9 kGy.It was validated that the experiment value and forecast value were approximate because the grafting ratio and average grafting efficiency were 130.2% and 80.4% respectively,and synthesis score was 19.78 for XG-g-AM prepared by optimal process conditions.So the forecast model can preferably describe the relation between synthesis score and various influence factors.