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Fe和Co催化的碳-碳偶联反应的最新进展
  • ISSN号：0253-2786
  • 期刊名称：《有机化学》
  • 时间：0
  • 分类：O643.36[理学—物理化学;理学—化学]
  • 作者机构：[1]中国科学技术大学化学系,合肥230026
  • 相关基金：国家自然科学基金（Nos.20472079,20602034）资助项目.
作者： 王晨[1], 傅尧[1], 刘磊[1], 郭庆祥[1]
关键词： 铁, 钴, 碳-碳偶联反应, 催化, 绿色化学, Fe, Co, C-C coupling reaction, catalysis, green chemistry
中文摘要：

作为廉价而且低毒的金属，Fe和Co是发展催化剂的理想元素．同时由于Fe和Co有着多种氧化还原价态，它们的催化化学应该具有极其丰富的内容．然而由于种种原因，Fe和Co的催化剂很少得到有机化学家的关注．直到最近几年，人们才发现Fe和Co的催化剂可以很好地催化碳-碳偶联反应．综述了Fe和Co催化碳-碳偶联反应的条件、产率和选择性；探讨了这些新奇反应的可能机理；并介绍了这些反应在复杂化合物合成中的应用．

英文摘要：

As inexpensive and relatively nontoxic metals, Fe and Co are ideal elements for the development of catalysts. Because they have multiple redox states, Fe and Co are also anticipated to have very rich catalytic chemistry. Nonetheless, very little attention has been paid to the catalysis of Fe and Co. The present review surveys reaction conditions, yields and selectivity of the C-C coupling reactions. Possible mechanisms of these intriguing reactions are discussed. Applications of these new reactions to complex molecule synthesis are also described.

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期刊信息
  • 《有机化学》
  • 中国科技核心期刊
  • 主管单位:
  • 主办单位:中国化学会 中国科学院上海有机化学研究所
  • 主编：陈庆云
  • 地址：上海市枫林路354号
  • 邮编：200032
  • 邮箱：bianji@mail.sioc.ac.cn
  • 电话：021-54925244
  • 国际标准刊号：ISSN：0253-2786
  • 国内统一刊号：ISSN：31-1321/O6
  • 邮发代号:4-285
  • 获奖情况:
  • 中国期刊方阵“双效”期刊
  • 国内外数据库收录:
  • 俄罗斯文摘杂志,美国化学文摘（网络版）,荷兰文摘与引文数据库,美国科学引文索引（扩展库）,日本日本科学技术振兴机构数据库,中国中国科技核心期刊,中国北大核心期刊（2004版）,中国北大核心期刊（2008版）,中国北大核心期刊（2011版）,中国北大核心期刊（2014版）,中国北大核心期刊（2000版）
  • 被引量:14408