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Dissolution of Al_2TiO_5 inclusions in CaO-SiO_2-Al_2O_3 slags at 1823 K
  • ISSN号:1672-7207
  • 期刊名称:《中南大学学报:自然科学版》
  • 时间:0
  • 分类:TF77[冶金工程—钢铁冶金]
  • 作者机构:[1]东北大学多金属共生矿生态化冶金教育部重点实验室,辽宁沈阳110819
  • 相关基金:国家自然科学基金资助项目(50904017);中央高校基本科研业务费专项资金资助项目(N120602005);中国博士后科学基金资助项目(2011M500823).
中文摘要:

采用定量金相及SEM—EDS手段对Mg,Zr及Mg—Zr处理FH40级船板铸钢中夹杂物粒径分布、平均粒径、总数量、总面积及成分、形貌等特征进行系统研究.结果表明,Mg,Zr及Mg—Zr处理后铸锭夹杂物平均粒径下降,夹杂物总数量增加.Mg的质量分数为0.024%时,夹杂物中MgO平均质量分数为12.57%,变质不充分;Mg的质量分数增加至0.072%后,夹杂物中MgO平均质量分数为35.58%,实现了氧化铝向MgO·Al2O3的充分变质,且夹杂物粒径明显减小.0.03%Zr处理后,铸锭夹杂物以Al2O3+MnS,Al—Zr—O+MnS为主;低Mg+高Zr,高Mg+低Zr,高Mg+高Zr处理炉次试验钢铸锭中均发现了含Zr夹杂物,其中高Mg+高Zr炉次形成了Zr02夹杂,该类夹杂物被MgO·Al2O3包裹,团聚现象明显.

英文摘要:

The characteristics such as particle size distribution, average particle size, total amount and chemical composition of FH40 ship-building steels formed by Mg, Zr, Mg-Zr combined treatment were investigated by the quantitative metallographic and SEM-EDS methods. The results showed that the average particle size decreased while the total amount of inclusions increased after Mg, Zr, Mg-Zr treatment. With 0. 024% Mg addition, the average mass fraction of MgO was 12.57% in the inclusions, which was not fully modified; With 0. 072% Mg addition, the average mass fraction of MgO was 35.58% , in the inclusions which meant that A1203 completely translated into MgO.Al2O3, and the size of inclusions decreased obviously. With 0.03% Zr addition, the main inclusions of the ingot were mainly A1203 + MnS, A1-Zr-O + MnS. The Zr-containing inclusions were all found after Mg-Zr combined treatment with the amount of the Mg and Zr additions changed as follow low Mg + high Zr, high Mg + low Zr and high Mg + high Zr. Especially, ZrO2 inclusions wrapped with MgO. A1203were found in the high Mg + high Zr treated steel with the apparent tendency to be aggregated.

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期刊信息
  • 《中南大学学报:自然科学版》
  • 北大核心期刊(2011版)
  • 主管单位:教育部
  • 主办单位:中南大学
  • 主编:黄伯云
  • 地址:湖南长沙中南大学校本部
  • 邮编:410083
  • 邮箱:zngdxb@csu.edu.cn
  • 电话:0731-88879765
  • 国际标准刊号:ISSN:1672-7207
  • 国内统一刊号:ISSN:43-1426/N
  • 邮发代号:42-19
  • 获奖情况:
  • 首届全国优秀科技期刊评比一等奖,第二届全国优秀科技期刊评比一等奖,首届中国有色金属工业优秀科技期刊评比一等奖
  • 国内外数据库收录:
  • 美国化学文摘(网络版),荷兰文摘与引文数据库,美国工程索引,英国科学文摘数据库,中国中国科技核心期刊,中国北大核心期刊(2008版),中国北大核心期刊(2011版),中国北大核心期刊(2014版)
  • 被引量:20874