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吸附质共存与浓度变化对植物基质N、P吸附的影响
  • ISSN号:1000-0275
  • 期刊名称:《农业现代化研究》
  • 时间:0
  • 分类:X712[环境科学与工程—环境工程]
  • 作者机构:[1]广西大学林学院,广西南宁530004, [2]中国科学院亚热带农业生态研究所亚热带农业生态过程重点实验室,湖南长沙410125
  • 相关基金:国家自然科学基金项目(31360134);广西科学研究与技术开发计划(桂科转1599001-6).
中文摘要:

采用静态吸附方法,研究了吸附质浓度、离子共存对水葫芦鲜样(ECF)和干样(ECD)、稻草干样(OSD)和杉木屑干样(CLD)的氮磷吸附影响过程与特征。结果表明:1)在单一吸附质试验条件下,所有基质对磷的去除率随吸附液PO4--P浓度升高而逐渐下降,ECF和ECD对NO3--N或NH4 -N的吸附率则随吸附质浓度升高呈现出先降后升再降的趋势,而OSD和CLD对NO3--N的吸附则随吸附质浓度升高而不断升高。植物基质对氮磷去除率均随吸附时间延长而逐渐下降,在第4 h和第5 h,去除率降至10%以下。吸附质浓度由0.01 mol/L升高至0.12 mol/L,基质对NO3--N的吸附累积量增至8.0-33.0倍,而对NH4 -N则为4.8-6.8倍。ECF对PO4^--P、NO3^--N和NH4 -N的平均去除率比OSD分别高47.5%、46.9%和22.8%,比CLD分别高98.2%、76.9%和161.4%。2)吸附质共存强烈抑制了ECF、ECD、OSD对氮磷的吸附,而促进了CLD对NH4 -N的吸附。3)水葫芦鲜样对氮磷的吸附能力最强,其PO4^--P、NO3^--N、NH4 -N的饱和吸附量分别为9.7 mg/g、66.3 mg/g和47.9 mg/g,是水稻秸秆的1.8、1.5和1.9倍;新鲜水葫芦晒干会导致其氮磷饱和吸附量下降51%-60%。

英文摘要:

The objective of this study was to identify the purifying effect and adsorption characteristics of porous plant substrates on high nitrogen and phosphorus in water. For this purpose, the adsorption process and characteristic of nitrogen and phosphorus plant substrates, including fresh Eichhornia crassipes (ECF) and dry(ECD), dry straw(OSD) and the dry sawdust of Cunninghamia lanceolata (CLD), were determined by static adsorption experiment. The effects of initial concentration of nitrogen and phosphorus and coexisting ions on adsorption process and characteristic were also explored. The single adsorbate experiment indicated that the removal efficiency of PO4--P decreased with the rising of initial PO4--P concentration. Besides, the removal efficiency of NO3--N and NH4 -N decreased first and then increased with the rising of initial concentration. In addition, the removal efficiency of nitrogen and phosphorus which was adsorbed by plant substrates decreased with time, and the removal was lower than 10% at 4th h and 5th h. The substrates adsorption capacity of NO3--N increased to 8.0-33.0 times with the concentration increasing from 0.01 to 0.12 mol/L, and the adsorption capacity of NH4 -N increased to 4.8 - 6.8 times. The average removal efficiencies of ECF were higher than that of OSD by 47.5%, 46.9%, 22.8% , and higher than that of CLD by 98.2%, 76.9%, 161.4%, respectively, for PO4--P, NO3--N, NH4 -N. Coexisting ions significantly prohibited nitrogen and phosphorus adsorption by plant substrates, whereas the NH4 -N sorption by CLD increased with PO4^--P and NO3^--N coexisted. The adsorption capacity of fresh water hyacinth was the highest. The maximum adsorption capacities of PO4^--P, NO3^--N, NH4 -N were 9.7, 66.3, and 47.9 mg/g, which were 1.8, 1.5, and 1.9 times higher than that of straw. Compared to the maximum adsorption capacities of fresh water hyacinth, the dry one decreased by 51%-60%.

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期刊信息
  • 《农业现代化研究》
  • 北大核心期刊(2011版)
  • 主管单位:中国科学院
  • 主办单位:中国科学院农业研究委员会 中国科学院亚热带农业生态研究所
  • 主编:王克林
  • 地址:湖南长沙市芙蓉区远大二路644号
  • 邮编:410125
  • 邮箱:nyxdhyj@isa.ac.cn
  • 电话:0731-4615231
  • 国际标准刊号:ISSN:1000-0275
  • 国内统一刊号:ISSN:43-1132/S
  • 邮发代号:42-46
  • 获奖情况:
  • 中国科学院优秀期刊,湖南省一级期刊,湖南省优秀期刊
  • 国内外数据库收录:
  • 英国农业与生物科学研究中心文摘,日本日本科学技术振兴机构数据库,中国中国人文社科核心期刊,中国中国科技核心期刊,中国北大核心期刊(2004版),中国北大核心期刊(2008版),中国北大核心期刊(2011版),中国北大核心期刊(2014版),中国北大核心期刊(2000版)
  • 被引量:19728