中文摘要：

试图在根值 Scrophulariae (Scrophularia ningpoensis ) 分析主要成分。方法根值 Scrophulariae 被结合的 HPLC 分析 electrospray 电离四极 time-of-flight 双人脚踏车团 spectrometry (ESI-Q-TOF MS/MS ) 。混合物被 HPLC 用 C18 列和 acetonitrile 和 0.1 %(V/V ) 的坡度 elution 分开醋性酸水。否定离子模式被采用。36 全部的结果 A 加重，包括十四 iridoid glycosides，十九 phenylpropanoid glycosides，和三器官的酸，基于先锋和产品离子的精确集体测量从根值 Scrophulariae 被识别。21 成分被参考标准或以前的出版物把他们的保留时间(tR ) 和 ESI-MS/MS 数据与那些作比较识别，当十五混合物尝试性地根据他们负担得起足够的结构的信息的 Q-TOF MS/MS 数据被识别或推出时。这学习，这被相信的结论为在根值 Scrophulariae 的成分的鉴定是有用的，以及联系植物和复杂药方。

英文摘要：

AIM： To analyze the major constituents in Radix Scrophulariae （Scrophularia ningpoensis）. METHOD： Radix Scrophulariae was analyzed by HPLC coupled with electrospray ionization quadrupole time-of-flight tandem mass spectrometry （ESI-Q-TOF MS/MS）. Compounds were separated by HPLC using a C18 column and gradient elution of acetonitrile and 0.1% （V/V） acetic acid-water. Negative ion mode was employed. RESULTS： A total of thirty-six compounds, including fourteen iridoid glycosides, nineteen phenylpropanoid glycosides, and three organic acids, were identified from Radix Scrophulariae based on the accurate mass measurement of precursor and product ions. Twenty-one of the constituents were identified by comparing their retention times （tR） and ESI-MS/MS data with those of reference standards and/or previous publications, while another fifteen compounds were tentatively identified or deduced according to their Q-TOF MS/MS data which afforded sufficient structural information. CONCLUSION： It is believed that this study is useful for the identification of constituents in Radix Scrophulariae, as well as related plants and complex prescriptions.