中文摘要：

meso-Tetrakis-(p-methoxyphenyl ) 卟啉稀土元素氯化物，行(TMOPP ) Cl (行：Dy，惊讶， Tm， Yb，陆和 H2TMOPP：tetrakis-(p-methoxyphenyl ) 卟啉) ，被综合并且描绘。他们的作文，结构和性质被元素的分析学习，紫外线可见系列，红外线的系列，光系列，臼齿的传导力和热分析。卟啉的四个氮原子与四个协作数字被结合到一个中央稀土元素离子。lanthanide 离子在分子的飞机和氯化物离子在协作混合物的边界外面的卟啉上面躺。建筑群低于 200 是稳定的

英文摘要：

meso-Tetrakis-（p-methoxyphenyl）porphyrin rare earth chlorides, Ln（TMOPP）Cl （Ln： Dy, Ho, Tm, Yb, Lu and H2TMOPP： tetrakis-（p-methoxyphenyl）porphyrin）, were synthesized and characterized. Their composition, structure and properties were studied by elemental analyses, ultra-violet visible spectra, infrared spectra, luminescence spectra, molar conductances and thermal analysis. The four nitrogen atoms of the porphyrin are bonded to a central rare earth ion with four coordination numbers. The lanthanide ion lies above the porphyrin molecular plane and chloride ion is outside boundary of the coordination compound. Complexes are stable below 200℃ and do not contain small molecules （water or solvent）. Ultra-violet visible and infrared spectra were recorded and some of spectral bands were assigned. Surface photovoltaic spectroscopy （SPS） and electric-field induced surface photovoltaic spectroscopy （EFISPS） were measured. The spectral bands were assigned. The photovoltaic response is similar to the UV-visible absorption spectrum, therefore corresponding to analogous electron transition process.