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电化学诱导法制备二氧化硅薄膜材料
  • ISSN号:1004-4736
  • 期刊名称:武汉工程大学学报
  • 时间:2011.5.5
  • 页码:1-4
  • 分类:TQ150.1[化学工程—电化学工业]
  • 作者机构:[1]武汉工程大学化工与制药学院 绿色化工过程省部共建教育部重点实验室 湖北省新型反应器与绿色化学工艺重点实验室,湖北武汉430074
  • 相关基金:国家自然科学基金(20873097 21071113); 湖北省教育厅科研计划(重大项目 Z2009150); 武汉市学科带头人计划(200951830551)
  • 相关项目:固体基底上多层有序分子膜层间可控导入功能分子和金属离子的研究
作者: 陈勇|刘善堂|
中文摘要:

通过电化学诱导的溶胶-凝胶过程,以四甲氧基硅烷(TMOS)作为硅源,在氧化铟锡(ITO)电极表面制备了二氧化硅(SiO2)薄膜.使用扫描电镜(SEM)、紫外可见光谱(UV)和循环伏安法(CV)分别对薄膜的表面形貌、光吸收特性和导电性能进行了表征.结果表明:所施加的电压显著地影响SiO2薄膜的在固体表面上的生长.SEM图显示出在薄膜表面上没有明显的介孔结构.薄膜的紫外可见光谱在波长为430 nm处出现了SiO2分子的本征吸收峰,表明这固体表面上的材料主要是由SiO2构成的.循环伏安曲线证明该薄膜材料具有很高的电阻.这种电沉积的SiO2薄膜材料有望应用于分解有机污染物等领域.

英文摘要:

Silica thin films were electrodeposited on indium tin oxide electrode(ITO) by the way of electrochemical inducement with silica source of Tetramethoxysilane(TMOS).The surface morphology of films was characterized by Scanning Electron Microscope(SEM).The light absorption property and conductivity of films were characterized by Ultraviolet/Visible spectrum(UV) and Cyclic Voltammetry(CV).We showed that the applied potential significantly affected the formation of silica films.The images of SEM showed that there are no porous surfaces on the surface of thin films.A UV absorption peak at 430 nm was observed.It was mainly due to the intrinsic absorption of silica films,all of which indicated the component of this thin films is silicon dioxide.Cyclic voltammograms(CV) showed high electric resistance of the films.This electrochemically induced approach of preparation of films has been expected to use for decomposing organic pollutants.

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