中文摘要：

用5-（对-羟基苯基）-10,15,20-三（对-氯代苯基）卟啉为原料合成了以反丁烯二酰氯桥连的10,15,20-三（对-氯代苯基）卟啉二联体及其Zn,Cu,Co,Mn配合物,并用红外光谱、拉曼光谱、紫外光谱、质谱、核磁共振谱对其结构进行了表征.利用分子荧光光谱和表面光电压对其光学性质进行了研究.

英文摘要：

The 10,15,20-tri（p-chlorophenyl）porphyrin dimer was synthesized with（E）-2-butenedioyl di-chlorid as a bridge-linked reagent and its Zn,Cu,Co,Mn complexes were synthesized and characterized by means of IR,Raman,UV-Vis,MS,1H NMR and 13C NMR.The optical properties were studied by fluores-cence spectrometer and SPS（surface photovoltage spectroscopy）.