中文摘要：

以球状纳米Cu2O为核心，直接牺牲其毒面的部分Cu2O，与溶液中的均苯三羧酸（H3BTC）配体反应，原位生成具有核壳结构的Cu2O@HKUST-1材料。采用O2程序升温脱附（O2-TPD）、H2程序升温还原（H2-TPR）及C0氧化反应对Cu2O@HKUST-1核壳材料的抗氧化能力进行了研究，证明金属一有机框架材料（MOFs）HKUST-1对反应气体起到富集、缓释作用，保护Cu2O核不被氧化，显著提高了其抗氧化能力。

英文摘要：

Spherical nanometer Cu2O was employed as the core with partial of whose Cu2O on surface sacrificing, which reacted with benzene-1,3,5-triearboxylic acid （H3BTC） ligand in solution, forming the product of CUEO@HKUST-1 with core-shell structure in situ. The antioxidant ability of core-shell-structure CUEO@HKUST-1 was investigated by O2 temperature programmed desorption （O2-TPD）, H2 temperature programmed reduction （H2- TPR） and CO oxidation reaction. The result shows that the Cu2O antioxidant ability is significantly increased. The metal-organic frameworks （MOFs） HKUST-1 could protect Cu2O from oxidation because of its enrichment and slow-release of reacting gas.