位置:成果数据库 > 期刊 > 期刊详情页
A micro-sphere catalyst complex with nano CaCO3 precursor for hydrogen production used in ReSER process
  • ISSN号:1003-9015
  • 期刊名称:《高校化学工程学报》
  • 时间:0
  • 分类:TQ423.2[化学工程] TS733.9[轻工技术与工程—制浆造纸工程]
  • 作者机构:[1]Department of Chemical and Biological Engineering, Zhejiang-University, Hangzhou 310027, China
  • 相关基金:Foundation item: The authors are grateful to the supports from Sinopec of China and from National Science Foundation of China (NSFC) under contracts No. 20676119 and No. 20876142 respectively.
中文摘要:

这篇论文在提高的反应吸着为氢生产描述微范围的催化建筑群的准备和评估改过( ReSER )催化建筑群由一种水花技术做了的 process.The 有双功能作为在 ReSER process.The 摩擦特征使用的吸附材料作为催化材料和 CaO 包含 Ni 为当 CaO 的一位先锋显示出理想的 durabilit ,使用的商业 used.The nano CaCO3 材料催化建筑群中是可接受的

英文摘要:

This paper describes the preparation and evaluation of a micro-sphere catalytic complex for the hydrogen production in a Reactive Sorption Enhanced Reforming (ReSER) process. The catalytic complex made by a spray technique has a dual function containing Ni as a catalytic material and CaO as an adsorption material used in the ReSER process. The attrition characteristics of the catalytic complex are acceptable for the commercial used. The nano GaCO3 material used as a precursor of CaO showed a desirable durability with a CO2 sorption capacity of 0.6 mol CO2/kg after 10 repeating cycles under the carbonation temperature of 600 ℃, a CO2 partial pressure of 0.02 MPa, and a calcination temperature of 750 ℃ in N2 measured by a thermal gravimetric analyzer. The testing of the catalytic complex for ReSER showed a hydrogen yield of over 95 % (v/v) in the laboratory fixed fluidized bed reactor. The catalytic system has an attractive prospect in the ReSER process for hydrogen production, especially in the fluidized mode where reactor and regenerator combined in a cycling process.

同期刊论文项目
同项目期刊论文
期刊信息
  • 《高校化学工程学报》
  • 北大核心期刊(2011版)
  • 主管单位:国家教育部
  • 主办单位:浙江大学
  • 主编:陈纪忠
  • 地址:杭州浙大路38号浙江大学玉泉校区化工系
  • 邮编:310027
  • 邮箱:gxhgxb@zju.edu.cn
  • 电话:0571-87951235
  • 国际标准刊号:ISSN:1003-9015
  • 国内统一刊号:ISSN:33-1141/TQ
  • 邮发代号:
  • 获奖情况:
  • 2000年获浙江省科技期刊编辑学会颁发的“1999-200...,中国期刊方阵“双效”期刊
  • 国内外数据库收录:
  • 俄罗斯文摘杂志,美国化学文摘(网络版),荷兰文摘与引文数据库,美国工程索引,美国剑桥科学文摘,日本日本科学技术振兴机构数据库,中国中国科技核心期刊,中国北大核心期刊(2004版),中国北大核心期刊(2008版),中国北大核心期刊(2011版),中国北大核心期刊(2014版),中国北大核心期刊(2000版)
  • 被引量:14205