中文摘要：

质子化N，N,N＇,N＇-四苄基乙二胺可与[Fe（CN）6]^3-，[SnCl6]^2-和[TeCl6]^2-二次球形配位分别形成可容纳客体分子的包结物晶体（1）～（3）．晶体（1）通过NH^＋…NC^-，NH^＋…π（NC）和CH…π（NC）组合合成子，构筑了亲水性层柱隧道结构，孔径尺寸为1．03nm×1．12nm，两个乙醇分子和两个水分子填充于隧道中；晶体（2）通过CH…Cl^-合成子，构筑了亲水性层间隧道结构，孔径尺寸为0．94nm×0．73nm，三个水分子和两个氯离子填充于隧道中；晶体（3）的结构与晶体（2）相似，也是通过CH…Cl^-合成子，构筑了层间亲水性隧道结构，孔径尺寸为0．94nm×0．72nm，两个水分子填充于隧道中．

英文摘要：

Protonated N,N,N＇,N＇-tetrabenzyl-ethylenediamine can form inclusion crystals （1）-（3） with [Fe（CN）6]^3-, [SnCl6]^2- and [TeCl6]^2- by second-sphere coordination, respectively. The crystal （1）, through the combination of synthons of NH^＋…NC^- , NH^＋…π（NC） and CH…π（NC）, constructing a hydrophilic pillared layer channel with channel size of 1.03 nm × 1.12 nm, which can accommodate two alcohol molecules and two water molecules; the crystal （2） is endowed with hydrophilic channels between layers through C-H…Cl^- synthons, with channel size of 0.94 nm × 0.73 nm, in which three water molecules and two Cl^- anions are packed; the structure of crystal （3） is similar to that of crystal （2）, a hydrophilic channel between layer structures is constructed by C-H…Cl^- synthons, with channel size of 0.94 nm×0.72 nm, and two water molecules are filled within the channel between layers.