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Cu纳米线的高温原位加热XRD研究
  • 期刊名称:核技术, 30, 565-567, (2007)
  • 时间:0
  • 分类:O722[理学—晶体学]
  • 作者机构:[1]中国科学院高能物理研究所,北京100049, [2]中国科学院固体物理研究所,合肥230031, [3]中国科学院研究生院,北京100049
  • 相关基金:国家自然科学基金(10374087)资助
  • 相关项目:应用同步辐射技术研究原位加热过程中的纳米颗粒结构及热稳定性规
中文摘要:

采用电化学沉积方法,在孔径约50nm的阳极氧化铝模板中生长Cu纳米线,经过高温原位加热XRD实验,证实了其热膨胀系数约2.6×10^5^-1,稍大于块体Cu,与文献中Cu纳米线近似为零的热膨胀系数有明显的区别。对这一现象进行了简要的讨论后得出结论认为:基于模板生长的Cu纳米线,其晶格完整程度是决定热膨胀的重要因素。

英文摘要:

Cu nanowires with diameter of about 50 nm were electrochemically deposited in anodic alumina membrane. An in-situ high-temperature XR.D technique was used to measure the crystalline structures. The results demonstrate that these Cu nanowires have a thermal expansion coefficient of about 2.6×10^5 K^-1, which is a little larger than the bulk's one. These polycrystalline Cu nanowires are completely different from the zero-expansion Cu nanowires reported in previous reference. It is concluded that the thermal expansion coefficient is dependent on the crystalline perfection in nanowires.

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