为了解决现有高吸水树脂(SAP)产品耐盐能力低、生物降解性差的缺点,利用反相悬浮聚合法,将羧甲基纤维素(CMC)与丙烯酰胺(AM)和甲基丙烯酰氧乙基三甲基氯化铵(MAETAC)接枝共聚,创新合成了分子中同时含有阳离子和非离子亲水基团的CMC改性高吸水树脂(ICAM)。对合成反应的影响因素进行了探讨和研究,得出的反相悬浮聚合法制备ICAM树脂的优化工艺条件为油水比2:1,分散剂采用Span60与Tween80复配,二者质量比为3:1,总用量为水相质量的5%,CMC加入量为单体的5%,单体水溶液体系pH值为4,引发剂(NaHSO3、(NH4)2S2O8)用量为单体的2.5%,交联剂N,N'-亚甲基双丙烯酰胺(NMBA)用量为单体的0.5%,反应温度为65℃,反应时间2h。该条件下得到的树脂产品吸蒸馏水倍率为657g/g、吸0.9%NaCl溶液为116g/g。
Acrylamide (AM) , and [ 2-(methylacL'yloyloxy) ethyl] trimethylammonium chloride (MAETAC) were grafted onto carboxymethyl cellulose (CMC) to prepare cellulose-modified cationic superabsorbent polymers (SAP) by inverse suspension copolymerization. Factors affecting water-absorbent capacity were investigated in detail, which were found to be as follows: ratio of oil to water 2:1, dosage of Span 60 andTween 80(3:1), 5 % of water phase, pH value 4, CMC dosage5 %, content of initiator( NaHSO3, ( NH4)2S2O8 )2.5 % , and erosslinking agent 0. 5 % of the weight of monomers, reaction temperature 65 ℃, reaction time 2 h. The cellulose-modified cationic SAPs prepared under optimum conditions were obtained which have the absorbent capacity of 657 times their own weight in distilled water and 116 times in 0. 9 % salt solution under optimized synthesis condition.