位置:成果数据库 > 期刊 > 期刊详情页
一种新型检测饮用水中氰化物的方法
  • ISSN号:1009-6094
  • 期刊名称:《安全与环境学报》
  • 分类:X824[环境科学与工程—环境工程]
  • 作者机构:[1]北京大学深圳研究生院环境与能源学院深圳市重金属污染控制与资源化重点实验室,广东深圳518055, [2]北京大学环境科学与工程学院水沙科学教育部重点实验室,北京100871
  • 相关基金:国家自然科学基金项目(51379009)
中文摘要:

氰化物为剧毒物质,针对氰化物研究出一种快速、可视化检测方法是非常有必要的。研究发现,荧光分子Singapore Tongue(SGT-5)与Hg2+的混合体系(命名为Cyanogen Red,CNR)可以作为新的荧光传感器,对饮用水规定安全阈值内的CN-实现快速、可视化的检测。当水体中CN-浓度为0.210μmol/L时,CNR的荧光值与CN-浓度呈现良好线性关系(R2=0.998),并且肉眼可见其荧光红色随CN-浓度增大呈渐暗趋势。CNR对水体中常见的阴离子如Cl-,SO42-,CO32-,HCO3-,NO3-和PO4-单一体系和混合体系都具有选择性。通过对14种实际饮用水样中滴加10μmol/L CN-的准确测定,得出该方法相比较传统硝酸银滴定法具有许多优势,不但需样量少(100μL)、耗时短(1 min),而且检测限完全能够满足安全引用水中CN-的最大允许浓度1.9μmol/L。

英文摘要:

The paper is intended to present a novel method for quick and visual detection of the cyanide content in the drinking water known as Cyanogen Red (CNR) by way of combining the fluorescent molecules of Singapore Tongue (SGT -5) with Hg2+ . However, the traditional CN- detection method remains low efficient and time-consuming. In answering to this badly need, we have developed a method known as the quick, visualized testing method for testing the intensity of CNR fluorescence in the drink- ing water, which can help to make clear the tendency of the linear dependence On the concentration of CN - in the deionized water e- ven with the concentration of CN - being smaller than 10μmol/L. Furthermore, by irradiating CNR and CN- mixtures under 365 nm UV lamp, CN - can reduce the red color of CNR to a great extent and be visualized by the naked eyes. As a result, CNR fluorescent method shows a feature of being highly selective among the common anions present in the water containing CI- , SO42- , CO3- , HC03- , NO3- and PO4 , regardless of the single anion or the mixed system. What is more, adding 10 μmol/L CN- to the 14 kinds of real water samples, we have found that CNR fluorescent method tends to be more accurately measurable than it can be done with the traditional CN- detection method. Besides, the newly developed CNR detection method by us proves to be more advantageous, for example, the samples determined by the newly developed method are much smaller in size (only 100μL) , determining much faster (1 min) and lower in detection minimal limits. In addition, it is capable to meet the need of the maximal concentration of 1.9μmol/L CN- as is demanded in the safetyuse drinking water.

同期刊论文项目
同项目期刊论文
期刊信息
  • 《安全与环境学报》
  • 北大核心期刊(2011版)
  • 主管单位:中国兵器工业集团公司
  • 主办单位:北京理工大学 中国环境科学学会 中国职业安全健康协会
  • 主编:冯长根
  • 地址:北京市海淀区中关村南大街5号
  • 邮编:100081
  • 邮箱:aqyhjxb@263.net;aqyhjxb@wuma.com.cn
  • 电话:010-68913997
  • 国际标准刊号:ISSN:1009-6094
  • 国内统一刊号:ISSN:11-4537/X
  • 邮发代号:2-770
  • 获奖情况:
  • 获首届《CAJ-CD》执行优秀期刊奖,中国科技论文统计源期刊
  • 国内外数据库收录:
  • 美国化学文摘(网络版),中国中国科技核心期刊,中国北大核心期刊(2008版),中国北大核心期刊(2011版),中国北大核心期刊(2014版)
  • 被引量:17182