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Synthesis, characterization and photoactivity of bi-crystalline mesoporous TiO2
  • ISSN号:2095-025X
  • 期刊名称:《材料科学前沿:英文版》
  • 分类:TQ134.1[化学工程—无机化工] O643.36[理学—物理化学;理学—化学]
  • 作者机构:[1]Key Laboratory for Anisotropy and Texture of Materials of Ministry of Education (ATM), Northeastern University Shenyang 110819, China, [2]School of Materials and Metallurgy, Northeastern University, Shenyang 110819, China
  • 相关基金:Acknowledgements This work was supported by the National Natural Science Foundation of China (Grant Nos. 21201030, 21471026 and 51272039), the Fundamental Research Funds for the Central Universities (N141005001, L1502020 and N130810003) and the Liaoning Province Innovation Funds (Grant No. 2014020030).
中文摘要:

Mesoporous titania (meso-TiO 2) 由于它的万用的潜在的应用收到了广泛的注意。这份报纸用 peroxo 为 meso-TiO 2 的制造报导一条低温度的 templating 途径巨人的酸(PTA ) 大音阶的第五音作为先锋和 Pluronic P123 作为 nonionic 模板。TGA, XRD, N 2 吸着, FE-SEM 和 HRTEM 被用来描绘获得的样品。结果与高表面区域显示出那 meso-TiO 2 直到 163 m 2 汣獥 ?? 坍乃吗??

英文摘要:

Mesoporous titania (meso-TiO2) has received extensive attention owing to its versatile potential applications. This paper reports a low-temperature templating approach for the fabrication of meso-TiO2 using the peroxo titanic acid (PTA) sol as precursor and Pluronic P123 as nonionic template. The TGA, XRD, N2 sorption, FE-SEM and HRTEM were used to characterize the obtained samples. The results showed that meso-TiO2 with high surface area up to 163 m2.g^-1 and large pore volume of 0.65 cm3.^-1 can be obtained. The mesopore sizes can be varied between 13 and 20 nm via this synthesis approach. The amount of P123 and the calcination conditions were found to have great influence on the mesoporous and crystalline structures of meso-TiO2. The photocatalytic activity testing clearly shows that the high surface area and bi-crystallinity phases of meso-TiO2 play important roles in enhancing photocatalytic properties of meso-TiO2 in photo-decomposing Rhodamine B in water.

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期刊信息
  • 《材料科学前沿:英文版》
  • 主管单位:中华人民共和国教育部
  • 主办单位:高等教育出版社
  • 主编:
  • 地址:北京市朝阳区惠新东街4号富盛大厦15层
  • 邮编:100029
  • 邮箱:
  • 电话:010-58556485
  • 国际标准刊号:ISSN:2095-025X
  • 国内统一刊号:ISSN:11-5985/TB
  • 邮发代号:80-974
  • 获奖情况:
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  • 被引量:7