中文摘要：

使用聚丙烯酸接枝改性聚四氟乙烯（PAA-g-PTFE）纤维分别与Fe3＋及其与Cu2＋的混合物反应制备改性PTFE纤维铁和铁铜双金属配合物，并分别使用傅里变换叶红外（FTlR）光谱和紫外-可见（uv-vis）漫反射光谱（DRS）对两种配合物的化学结构和光吸收性能进行表征．然后将两种配合物分别作为非均相光Fenton反应催化剂应用于典型偶氮染料活性蓝222氧化降解反应中，考察和比较了二者在不同pH介质中对降解反应的催化作用．结果表明，在有或无Cu2＋的存在条件下，一个Fe3＋能够与三个PAA-g-PTFE表面的6个羧基发生反应形成配合物，并且它们在紫外和可见光区表现出好的光吸收特性．当两种金属离子共存时Cu2＋比Fe3＋更容易与PAA-g-PTFE发生配位反应形成铁铜双金属配合物．在可见光辐射下PAA-g-PTFE铁配合物对不同pH水溶液中染料降解反应均表现出显著的催化作用，但是溶液pH的升高不利于配合物催化活性的发挥．而配合物中铁离子含量提高特别是引入Cu2＋作为助金属离子能够较大幅度地改善其在高pH范围内的催化活性和重复利用性．

英文摘要：

Polyacrylic acid grafted polytetrafluoroethylene （PAA-g-PTFE） fibers were coordinated with Fe3＋ ions and with a mixture of Cu2＋ and Fe3＋ ions to prepare PAA-g-PTFE Fe and Cu-Fe bimetallic complexes. The chemical structures and light adsorption properties of the complexes were characterized using Fourier transform infrared （FTIR） spectrometry and UV-Vis diffuse reflection spectroscopy （DRS）, respectively. The complexes were used as heterogeneous photo-Fenton catalysts in the oxidative degradation of the azo dye, Reactive Blue 222, in different pH aqueous media. The results indicate that Fe3＋coordinates with six carboxyl groups grafted on the surface of PAA-g-PTFE in the presence or absence of Cu2＋ ion, and improved light adsorption properties are achieved in the UV and visible regions. When both metal ions coexist in solution, the Cu2＋ ion coordinates more easily with PAA-g-PTFE than Fe3＋ to produce a PAA-g-PTFE Cu-Fe bimetallic complex. Moreover, PAA-g-PTFE Fe significantly increases the degradation of Reactive Blue 222 in the pH range 3-9 under visible irradiation. However, at high pH conditions （〉7） the catalytic ability is reduced. Increasing the Fe content, and especially incorporating Cu2＋ ions in the complex, dramatically improves the catalytic reusability at high pH value.