采用活性钎料TiZrNiCu对TiBw/TC4钛合金和C/C复合材料进行了钎焊连接,借助SEM,EDS,XRD等分析手段研究了钎焊工艺参数对接头界面组织结构的影响.结果表明,采用TiZrNiCu钎料可以实现对两种材料的连接,接头典型的界面结构为:C/C复合材料/TiC+(Ti,Zr)2(Cu,Ni)/Ti(s,s)+(Ti,Zr)2(Cu,Ni)/TiBw/TC4钛合金.随着连接温度的升高或保温时间的延长,钎焊接头界面生成产物的种类并没有发生改变,但C/C复合材料侧TiC反应层逐渐变得连续且厚度逐步增加,α-Ti枝状晶变得粗大且数量增多,Ti(s,s)+(Ti,Zr)2(Cu,Ni)层逐渐变宽,(Ti,Zr)2(Cu,Ni)逐步分散在Ti(s,s)中.
The active filler containing TiZrNiCu was used to join TiBw/TC4 alloy and C/C composite.The effect of the brazing parameters on the interfacial microstructure was studied by SEM,EDS,and XRD.The results show that the typical interfacial structure of the joint is C/C composites/TiC+(Ti,Zr)2(Cu,Ni)/Ti(s,s)+(Ti,Zr)2(Cu,Ni)/TiBw/TC4 alloy.With the increasing of brazing temperature or holding time,the type of the interfacial products in the brazing joint did not change,but the reaction layer of TiC near the C/C composites became continuous and thickness gradually increased,α-Ti dendrites became thicker and the number increased.The layer of Ti(s,s)+(Ti,Zr)2(Cu,Ni) became wider,the phase(Ti,Zr)2(Cu,Ni) gradually dispersed in Ti(s,s).