从低等级软锰矿的锰的减少的沥滤在的动力学冲淡硫磺的酸面对糖蜜酒精,废水被调查。缩小的核心模型被使用确定沥滤上的反应参数的效果评价。有反应温度的沥滤的率增加,在糖蜜白酒废水增加和矿石粒子的 H2SO4 和有机物的集中缩放减少。沥滤的过程跟随一个缩小的核心模型的动力学,明显的激活精力是 57.5 kJ 瑣 ??鎀 吗??
The kinetics of reductive leaching of manganese from low grade pyrolusite in dilute sulfuric acid in the presence of molasses alcohol wastewater was investigated. The shrinking core model was applied to quantify the effects of reaction parameters on leaching rate. The leaching rate increases with reaction temperature, concentrations of H 2 SO 4 and organic matter in molasses alcohol wastewater increase and ore particle size decreases. The leaching process follows the kinetics of a shrinking core model and the apparent activation energy is 57.5 kJ·mol –1 . The experimental results indicate a reaction order of 0.52 for H2SO4 concentration and 0.90 for chemical oxygen demand (COD) of molasses alcohol wastewater. It is concluded that the reductive leaching of pyrolusite with molasses alcohol wastewater is controlled by the diffusion through the ash/inert layer composed of the associated minerals.