在黔东南从江宰便地区进行地质填图过程中发现一处镁铁-超镁铁质岩体,该岩体属新元古代钙碱质岩系,矿物成分主要为长石、辉石和绿泥石等。其主量成分以高Na2O(5.04%-6.64%),CaO(0.76%-6.67%)和MgO(6.79%-7.88%),低TiO2(0.30%-0.4%),贫K2O(0.10%-0.29%)和P2O5(0.04%-0.05%)为特征。稀土总量ΣREE较高,为83.37×10^-6-164.97×10^-6,其LREE/HREE和(La/Yb)N变化较大,分别为3.50-7.25和2.90-7.58,表明轻和重稀土分馏较大,(La/Sm)N和(Gd/Yb)N相对较小,分别为1.81-3.19和1.22-1.53,表明轻稀土和重稀土内部分馏较小。在球粒陨石标准化图解上,为轻稀土富集,无Eu、Ce明显异常的平坦型;在原始地幔标准化曲线上出现较为明显的Nb、Ta负异常。微量元素及Y/Nb、Zr/Nb等参数暗示其为过渡-富集型地幔部分熔融的产物。综合研究表明该岩体形成于约800Ma的板内拉张环境,可能与导致Rodinia超大陆裂解的地幔柱有关。
The NeoProterozoic mafic-ultramafic rocks have been found in Zaibian area by geologic mapping.The mafic-ultramafic rocks are belonging to calc-alkaline;the minerals compositions are mainly feldspar,pyroxene and chlorite of the mafic-ultramafic rocks.The major elements have the characteristics of high contents of Na2O(5.04%-6.64%),CaO(0.76%-6.67%) and MgO(6.79%-7.88%),low contents of TiO2(0.30%~ 0.4%),and poor contents of K2O(0.10%-0.29%) and P2O5(0.04%-0.05%).The ΣREE is relatively high with 83.37×10^-6164.97 ×10^-6and the variety values of LREE/HREE and(La/Yb)N are relatively large,indicating that the fractionation between light rare earth elements and heavy rare earth elements is existent.However,the(La/Sm)N and(Gd/Yb)N are relatively less,with 1.81-3.19 and 1.22-1.53,respectively,reflecting that the fractionation of light rare earth elements and heavy rare earth elements is feebly.The Zaibian mafic-ultramafic rocks are LREE enriched,and have no evident Eu,with Ce abnormity,but have evident Nb,and anomaly negative Ta.The trace elements,Y/Nb,and Zr/Nb imply that the mafic-ultramafic rocks maybe originated from the Transition-Enriched-Mantle.The results indicate that the mafic-ultramafic rocks maybe formed in the inner-plate at about 800 Ma,and maybe related with the mantle plume which makes the Rodinia breakup.