位置:成果数据库 > 期刊 > 期刊详情页
硫酸体系中N_(235)萃钒的性能及其机制研究
  • ISSN号:0258-7076
  • 期刊名称:稀有金属
  • 时间:2015.4.15
  • 页码:337-342
  • 分类:TG146[金属学及工艺—金属材料;一般工业技术—材料科学与工程;金属学及工艺—金属学]
  • 作者机构:昆明理工大学冶金与能源工程学院,昆明650093
  • 相关基金:Project(2014CB643404)supported by the National Basic Research Program of China; Projects(51564030,51474117,51304093,51364022)supported by the National Natural Science Foundation of China; Project(0120150070)supported by Yunnan Applied Basic Reach Project,China; Project(ZD2014003)supported by the Education Department of Yunnan Province,China
  • 相关项目:有机磷类萃取剂结构-性能关系及萃取钒基础研究
中文摘要:

铁酸锌是锌中性浸出渣中的主要物相,热酸浸出是处理中性浸出渣的主要方法之一。研究了一种采用硫化锌精矿作为还原剂对锌中性浸出渣进行还原浸出的方法。研究发现,采用硫化锌精矿作为还原剂不仅能高效浸出锌中性浸出渣中的有价金属,而且同时实现溶液中Fe^3+向Fe^2+的还原。采用两段逆流浸出工艺,98.1%锌和97.5%铟被浸出,浸出液中Fe^2+/Fe^3+的摩尔比达到9.6。同时发现,浸出过程中铁和铜几乎完全浸出,而锡只有部分浸出。

英文摘要:

Zinc ferrite is the principal constituent in zinc neutral-leach residue(NLR) which is commonly treated by hot-acid leaching in electrolytic zinc plants. Reductive leaching of zinc ferrite with sphalerite concentrate as a reducing agent was performed. It was found that leaching of zinc ferrite in the presence of sphalerit concentrate was a viable process that effectively extracted zinc and indium and converted Fe^3+ into Fe^2+ at the same time. Reflux leaching tests by two stages were performed to achieve extractions of 98.1% for zinc and 97.5% for indium, and a Fe^2+/Fe^3+ molar ratio of 9.6 in leach solution was also obtained. The leaching behaviors of other elements, such as iron, copper and tin were also studied. The results showed that iron and copper were completely leached, whereas tin presented lower extraction values.

同期刊论文项目
同项目期刊论文
期刊信息
  • 《稀有金属》
  • 中国科技核心期刊
  • 主管单位:中国科学技术协会
  • 主办单位:北京有色金属研究总院
  • 主编:屠海令
  • 地址:北京新街口外大街2号
  • 邮编:100088
  • 邮箱:xxsf@grinm.com
  • 电话:010-82241917 62014832
  • 国际标准刊号:ISSN:0258-7076
  • 国内统一刊号:ISSN:11-2111/TF
  • 邮发代号:82-167
  • 获奖情况:
  • 中文核心期刊,冶金工业类核心期刊,中国科技论文统计源期刊
  • 国内外数据库收录:
  • 俄罗斯文摘杂志,美国化学文摘(网络版),荷兰文摘与引文数据库,美国工程索引,美国剑桥科学文摘,日本日本科学技术振兴机构数据库,中国中国科技核心期刊,中国北大核心期刊(2004版),中国北大核心期刊(2008版),中国北大核心期刊(2011版),中国北大核心期刊(2014版),中国北大核心期刊(2000版)
  • 被引量:13688