通过稀土氯化物与丙烯酸、1,10-菲罗啉进行配位反应,制得了含铕可聚合荧光配合物单体。通过红外、紫外、荧光、核磁、元素分析等方法对其结构和性能进行了表征。结果表明,产物符合预先设计的结构,具有可聚合活性和良好的荧光性能。
Based on traditional rare earth chloride, rare earth chloride was reacted with acrylic acid and 1,10 - phenanthroline. Europium containing polymerizable complex monomer was synthesized. The structure and properties were characterized by FT-IR, UV, fluorescence, 1H NMR, and elemental analysis. The results indicated that the products were consistent with predesigned structure with polymerizable activity and good fluorescence property.