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HC10_4酸介质中2-甲氨基-5-氯二苯甲酮萃取钯机理的研究
  • 时间:0
  • 分类:O614.82[理学—无机化学;理学—化学]
  • 作者机构:[1]安庆师范学院化学化工学院,安徽安庆246011
  • 相关基金:国家自然科学基金(20901004/B010303)资助.
中文摘要:

本文报道了HClO4体系中,2-甲氨基-5-氯二苯甲酮(R)萃取Pd的机理,考察了ClO-4浓度、Pd2+浓度和pH对Pd萃取率的影响,确定了萃合物组成为:[Pd·R2](ClO4)2。

英文摘要:

The extraction mechanism of Palladium from perchloric acid medium by 5-chloro-2-(methylamino)benzophenone(R)is studied.The ClO-4concentration,Pd2+concentration and the pH value to influence of the extraction rate of Pd are investigated.The composition of the extraction is[Pd·R2](ClO4)2as determined by slope method.The extraction mechanism of Palladium with 5-chloro-2-(methylamino)benzo-phenone based on UV-spectra is proved to be chelate extraction reaction as follows:2R(O)+Pb(A)2++2ClO4-4(A)=[Pd·R2](ClO4-)2(O).

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