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两个手性胶囊分子的氢键介质的动态共价键合成
  • ISSN号：0251-0790
  • 期刊名称：《高等学校化学学报》
  • 时间：0
  • 分类：O622[理学—有机化学;理学—化学]
  • 作者机构：[1]中国科学院上海有机化学研究所生命有机化学国家重点实验室,上海200032
  • 相关基金：国家“九七三”计划项目（批准号：2007CB808001）; 国家自然科学基金（批准号：20732007,20921091,20872167）; 上海市优秀学科带头人计划（批准号：09XD1405300）资助
作者： 徐晓娜[1], 王璐[1], 赵新[1], 黎占亭[1]
关键词： 氢键, 手性胶囊分子, 动态共价键化学, 折叠体, 亚胺形成, Hydrogen bond, Chiral capsule molecule, Dynamic covalent chemistry, Foldamer, Imine formation
中文摘要：

由手性环己-1,2-二胺衍生的手性双头基前体合成了2个手性的双层结构的胶囊化合物.设计前体带有氨基和醛基,它们被连接到2个分子内氢键诱导的折叠体片段上.分子内氢键通过促进6个亚胺键的形成导致2个大环板块的选择性.

英文摘要：

Two chiral two-layered capsular compounds have been synthesizied from chiral cyclohexane-1,2-diamine-derived dipodal precursors.The precursors bear both amino and aldehyde groups which are connected to two intramolecularly hydrogen bonded foldamer segments.Intramolecular hydrogen bonding facilitates the selective generation of two macrocyclic moieties by forming six imine bonds.

同期刊论文项目
化学生物学导向的有机合成
期刊论文 146 会议论文 1
有机分子的结构预组织与动态共价键化学
期刊论文 43
有序分子聚集体的组装及分子组装体中的能量传递、电子转移和化学转换
期刊论文 105 著作 2
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期刊信息
  • 《高等学校化学学报》
  • 北大核心期刊（2011版）
  • 主管单位:中华人民共和国教育部
  • 主办单位:吉林大学 南开大学
  • 主编：周其凤
  • 地址：吉林大学南胡校区
  • 邮编：130012
  • 邮箱：cjcu@jlu.edu.cn
  • 电话：0431-88499216
  • 国际标准刊号：ISSN：0251-0790
  • 国内统一刊号：ISSN：22-1131/O6
  • 邮发代号:12-40
  • 获奖情况:
  • 首届及第二届国家期刊奖,连续两届“百种中国杰出学术期刊”,中国期刊方阵“双高”期刊
  • 国内外数据库收录:
  • 俄罗斯文摘杂志,美国化学文摘（网络版）,荷兰文摘与引文数据库,美国工程索引,美国科学引文索引（扩展库）,日本日本科学技术振兴机构数据库,中国中国科技核心期刊,中国北大核心期刊（2004版）,中国北大核心期刊（2008版）,中国北大核心期刊（2011版）,中国北大核心期刊（2014版）,英国英国皇家化学学会文摘,中国北大核心期刊（2000版）
  • 被引量:50676