以合成的双金属配位聚合物Co(MAA)2/Ag(Ⅰ)纳米带为前驱体,制备了一维Ag@Co3O4纳米复合催化材料.采用傅里叶变换红外光谱(FTIR)、核磁共振氢谱(1H NMR)、粉末X射线衍射分析(XRD)、扫描电子显微镜(SEM)及透射电子显微镜(TEM)等方法对其结构进行了表征,结果表明,Ag纳米晶体和Co3O4纳米晶体均匀分布在Ag@Co3O4纳米带上.采用紫外-可见吸收光谱(UV-Vis)等方法考察了Ag@Co3O4纳米复合材料在亚甲基蓝(MB)染料还原反应中的催化性能,发现其具有良好的催化活性、循环稳定性及磁分离能力.
1D,magnetic Ag@Co3O4 nanocomposite catalysts were prepared using a synthesized precursor of bimetallic coordination polymers Co( MAA)2/ Ag( Ⅰ) nanoribbon. The structure of the obtained material was characterized by Fourier transform infrared spectroscopy( FTIR), proton nuclear magnetic resonance(-1H NMR),powder X-ray diffraction( XRD),scanning electron microscopy( SEM) and transmission electron microscope( TEM). The results suggested that both the Ag and Co3O4 nanocrystals distributed uniformly in the entire Ag@Co3O4 nanoribbon. Meanwhile,UV-Visible absorption spectrum( UV-Vis) was used to investigate the catalytic performance of Ag @Co3O4 nanocomposites towards the reduction of methyl blue( MB) dye by sodium borohydride( NaBH4). The results show that the material has excellent catalytic activity,cyclic stability and magnetic separation ability.