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Shell-driven Fine Structure Transition of Core Materials in Co@Au Core-shell Nanoparticles
  • 期刊名称:Nano-Micro Letters
  • 时间:0
  • 页码:235-242
  • 分类:TB383.1[一般工业技术—材料科学与工程]
  • 作者机构:School of Materials Science and Engineering, Beihang University
  • 相关基金:support from National Science Foundation of China(NSFC,Grant No.50971010);the Fundamental Research Funds for the Central Universities(YWF-11-03-Q-002)
  • 相关项目:程序变温微流体法制备核壳结构型纳米材料
中文摘要:

Co@Au core shell nanoparticles(NPs) of different shell thicknesses were fabricated by a combination of the displacement process and the reduction-deposition process in a microfluidic reactor. The effect of the shell thickness on the fine structures(local atom arrangement) of core materials was investigated by X-ray Absorption Near Edge Structure(XANES) and Extended X-ray Absorption Fine Structure(EXAFS).The results indicate that the shell thickness affects the fine structure of the core materials by causing atomic re-arrangement between the hexagonal close pack(hcp) and the face centered cubic(fcc) structure, and forming Co-Au bonds in the core-shell interface.

英文摘要:

Co@Au core shell nanoparticles (NPs) of different shell thicknesses were fabricated by a combination of the displacement process and the reduction-deposition process in a microfluidic reactor. The effect of the shell thickness on the fine structures (local atom arrangement) of core materials was investigated by X-ray Absorption Near Edge Structure (XANES) and Extended X-ray Absorption Fine Structure (EXAFS). The results indicate that the shell thickness affects the fine structure of the core materials by causing atomic re-arrangement between the hexagonal close pack (hcp) and the face centered cubic (fcc) structure, and forming Co-Au bonds in the core-shell interface.

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