中文摘要：

以1，1，6，6-四苯基-2，4—2-炔-1，6-二醇为主体分子，可简单、迅速地从青椒挥发油中选择分离出化学成分烯丙基茴香醚，基于挥发油的用量，收率为3．78％．IR，^1 HNMR，^13 CNMR光谱和单晶衍射证实了包结化合物结构，用气相色谱法评价了选择分离效果，分离的烯丙基茴香醚气相色谱纯度为94．5％．同时，主体分子形成的隧道框架对茴香醛具有识别作用，形成2：1（主／客）物质的量比的特殊结构包结物晶体，它是主客体分子物质的量比为1：2包结物的超分子异构体．

英文摘要：

1,1,6,6-Tetraphenylhexa-2,4-diyne-1,6-diol as host could selectively isolate 4-allylanisole from the crude volatile oil of Zanthoxylum schinifolium Sieb.et Zucc simply and rapidly, with a yeild of 3.78% based on the amount of volatile oil used. Inclusion compound structure was confirmed by IR, ^1 H NMR, ^13 C NMR and single crystal X-ray diffraction. Gas chromatographic method was used to assess the isolation effect and gas chromatographic purity of 4-allylanisole separated is 94.5%. At the same time, the channel framework formed by hosts could recognize p-anisaldehyde and form exceptive structural inclusion compound at a molar ratio of 2 ： 1 （host/guest）, which is a supramolecular isomer of inclusion compound at a molar ratio of 1 ： 2 （host/guest）.