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太湖沉积物-水界面生源要素迁移机制及定量化——2.磷释放的热力学机制及源-汇转换
  • ISSN号:1003-5427
  • 期刊名称:《湖泊科学》
  • 时间:0
  • 分类:P421.33[天文地球—大气科学及气象学] X524[环境科学与工程—环境工程]
  • 作者机构:[1]中国科学院南京地理与湖泊研究所,南京210008, [2]中国科学院研究生院,北京100039
  • 相关基金:中国科学院知识创新工程项目(KZCX3-SW-348,KZCX1-SW-12)、国家自然科学基金项目(20577053,40171083)共同资助.
中文摘要:

室内静态模拟不同温度下太湖15个湖区柱状沉积物磷酸根释放,分析了相应表层沉积物形态磷,以及梅梁湾间隙水中相关离子Al(Ⅲ)、Fe(Ⅱ)、Ca(Ⅱ)和PO34-含量的季节变化,研究表明,受陆源影响较大的泥区通常是太湖内源磷的稳定源;而在开敞度较大的湖区,由于表层沉积物胶体的物化吸附,使得温度对底泥磷释放的影响作用减弱,并易产生磷的“内汇”现象;在梅梁湾区成汇区,还加上春夏季藻类的局部超负荷需磷这一控制因素,从而使得太湖大部分泥区在一年中至少发生一次源-汇转换过程,化学热力学分析揭示,Al-P较之Fe-P和Ca-P更易在界面发生溶解可能是太湖表层沉积物Al-P与PO34--P释放速率呈显著相关(r=0,3858>r1-0,01,n=45)的内在原因,虽然沉积物中Fe-P有较高的释磷潜力,但浅水湖所营造的沉积物表层氧化层和广泛覆盖的无机胶体及粘土矿物的强吸附介质,可能是抑制沉积物中Fe-P释放成为优势的主要因素,估算太湖沉积物-水界面磷的净通量为899,4±573,6t/a,约占太湖磷入湖量的1/4-1/2,其中成汇通量约为-91,2±42,4t/a。

英文摘要:

Phosphate release from the core sediments of fifteen areas in Lake Taihu was simulated at different temperatures, and the phosphorus species in the sediments and seasonal variations of the relative ions, such as Al (Ⅲ) ,Fe( Ⅱ) ,Ca( Ⅰ) and PO4^3- were analyzed. The result shows that the areas affected greatly by terrestrial source are steady internal phosphorus sources in Lake Taihu. In more open areas, the physio-chemical adsorption of deposit colloid makes it weak that temperature have an influence on phosphorus release from sediment so as to produce "internal sink" of phosphorus. At sinking area in the Meiliang Bay, transnormal P demand of the local algae would be one of the most dominating reason of sink formation in addition in spring/summer seasons. There appeared source-sink transition at least once in most of the sediment areas. Chemical thermodynamic analysis reveals that Al-P dissolves more easily than Fe-P and Ca-P on the interface, which perhaps is inherent cause in respect to a marked relationship between Al-P in surface sediment and the phosphate release in Lake Taihu. Although Fe-P is considered to be a potential higher phosphorus release source , the oxidating layer formed on sediment surface and strong adsorbing media in shallow lakes, e.g. inorganic colloid and clay mineral, would be the dominant factors in Fe-P release. The net phosphorus flux, in the whole lake, was estimated about 899.4±573.6 t/a, accounting for about one quarter to half of phosphorus loadings, of which the sinking flux was approximately -91.2 ± 42.4 t/a.

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期刊信息
  • 《湖泊科学》
  • 北大核心期刊(2011版)
  • 主管单位:中国科学院
  • 主办单位:中国科学院南京地理与湖泊研究所 中国海洋湖沼学会
  • 主编:沈吉
  • 地址:南京市北京东路73号
  • 邮编:210008
  • 邮箱:jlakes@niglas.ac.cn
  • 电话:025-86882041 86882040
  • 国际标准刊号:ISSN:1003-5427
  • 国内统一刊号:ISSN:32-1331/P
  • 邮发代号:28-201
  • 获奖情况:
  • 中国科技核心期刊,中国期刊方阵“双效”期刊
  • 国内外数据库收录:
  • 俄罗斯文摘杂志,美国化学文摘(网络版),美国工程索引,美国地质文献预评数据库,美国剑桥科学文摘,美国生物科学数据库,英国动物学记录,日本日本科学技术振兴机构数据库,中国中国科技核心期刊,中国北大核心期刊(2004版),中国北大核心期刊(2008版),中国北大核心期刊(2011版),中国北大核心期刊(2014版)
  • 被引量:16668