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FA与FNA对两级UASB-A/O处理垃圾渗滤液短程硝化的影响
  • ISSN号:0438-1157
  • 期刊名称:化工学报
  • 时间:0
  • 页码:172-179
  • 分类:X703.1[环境科学与工程—环境工程]
  • 作者机构:[1]北京工业大学北京市水质科学与水环境恢复工程重点实验室,北京100124
  • 相关基金:基金项目:国家自然科学基金项目(50978003);北京市自然科学基金重点项目(8091001);北京市教委科技创新平台项目(PXM2008_014204_050843).
  • 相关项目:垃圾渗滤液短程与自养深度生物脱氮理论与技术
中文摘要:

采用两级UASB-A/O组合工艺处理实际高氨氮城市生活垃圾渗滤液,在获得稳定的有机物与氮同步去除的前提下,重点考察游离氨(FA)与游离亚硝酸(FNA)对短程硝化稳定性的影响。在UASB1中进行反硝化同时产甲烷以去除部分TN和部分COD,在UASB2通过产甲烷进一步去除COD,在A/O反应器中主要实现高氨氮的短程去除和剩余COD的降解。试验共进行104 d,历经短程硝化稳定、破坏和恢复3个阶段。结果表明,当最小FA浓度控制在3.1 mg.L^-1以上时,系统可维持稳定的短程硝化,NH+4-N去除率、NO-2-N积累率、TN去除率分别可达到99%、95%和86%。当FA浓度小于0.6 mg.L^-1时,在原水碱度充足且过曝气的条件下,仅依靠FA对NOB的抑制作用,难于维持短程硝化,NO2^--N积累率下降到29%。前两阶段的FNA浓度均低于0.011 mg.L^-1,没有对NOB起到抑制作用,而在第3阶段,FA浓度仍维持在较低浓度,但系统FNA浓度通过降低pH值而大幅度提高(最大值为0.414 mg.L^-1),从而利用FA和FNA的协同抑制作用迅速恢复并维持短程硝化,NO2^--N积累率升高到92%。可见FA与FNA是实现并维持城市生活垃圾渗滤液短程硝化的重要影响因素。

英文摘要:

A lab-scale two-stage UASB-A/O combined process was used to investigate the effect of free ammonia (FA) and free nitrite acid (FNA) on the short-cut nitrification of municipal landfill leachate rich in ammonia nitrogen (NH4^+-N) on the premise that the COD and nitrogen were removed simultaneously. The denitrifieation and methanogenesis were conducted in UASB1 simultaneously for the partial removal of TN and COD. The effluent COD of UASB1 was further removed in the UASB2 by methanogenesis. Subsequently, the denitrification of NOx^--N in the returned sludge using the residual COD and the short-cut nitrification was achieved in the A/O reactor. The experiment experienced three stages in 104 d. the stable short-cut nitrification, the damaged short-cut nitrification, and the recovered short-cut nitrification. The results showed that when the lowest FA was above 3. 1 mg · L^-1 the stable short-cut nitrification could be achieved and NH4^+ N removal efficiency, NO2^-N accumulation ratio and TN removal efficiency were 99%, 95% and 86%, respectively. When the FA was lower than 0.6 mg ·L^-1 with sufficient alkalinity and extended aeration, the short-cut nitration was damaged rapidly and NO2^--N accumulation ratio decreased to 29% due to the weak inhibition of low FA on NOB. FNA was lower than 0. 011 mg · L^- 1 at previous two stages, which led to the failure of inhibition on NOB. While FNA was increased considerably in the 3rd stage (the highest FNA was 0. 414 mg · L^- 1) by decreasing pH, the short-cut nitrification was recovered soon and maintained and NO2^--N accumulation ratio increased to 92% owing to the cooperative effect of FA and FNA. In brief, FA and FNA were important factors to achieve and maintain the short-cut nitrification of the municipal landfill leachate.

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期刊信息
  • 《化工学报》
  • 中国科技核心期刊
  • 主管单位:中国科学技术协会
  • 主办单位:中国化工学会 化学工业出版社
  • 主编:李静海
  • 地址:北京市东城区青年湖南街13号
  • 邮编:100011
  • 邮箱:hgxb126@126.com
  • 电话:010-64519485
  • 国际标准刊号:ISSN:0438-1157
  • 国内统一刊号:ISSN:11-1946/TQ
  • 邮发代号:2-370
  • 获奖情况:
  • 中国科协优秀期刊二等奖,化工部科技进步二等奖,北京全优期刊奖,中国期刊方阵“双效”期刊,第三届中国出版政府奖
  • 国内外数据库收录:
  • 俄罗斯文摘杂志,美国化学文摘(网络版),荷兰文摘与引文数据库,美国工程索引,日本日本科学技术振兴机构数据库,中国中国科技核心期刊,中国北大核心期刊(2004版),中国北大核心期刊(2008版),中国北大核心期刊(2011版),中国北大核心期刊(2014版),中国北大核心期刊(2000版)
  • 被引量:35185