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往复滑动干摩擦条件下碳烟颗粒的摩擦学特性研究
  • ISSN号:1004-0595
  • 期刊名称:《摩擦学学报》
  • 时间:0
  • 分类:TK6[动力工程及工程热物理—生物能]
  • 作者机构:[1]合肥工业大学摩擦学研究所,安徽合肥230009, [2]北方民族大学化学与化学工程学院,宁夏银川750021
  • 相关基金:国家高新技术发展“863”计划项目(2012AA051803); 国家自然科学基金(51275143)资助
中文摘要:

以稻壳为原料热解得到的生物质原油是一种成分复杂、物理化学性能不稳定的混合物,只有经过物理或化学改性的生物质燃料才可以在现代柴油机中应用。采用减压蒸馏的方式分离出生物质油轻质组分,在4个温度(150、250、350和150/350℃)和压力2MPa条件下,以MoS2为催化剂,在间歇反应釜中进行催化加氢改性。从改性油产率、加氢前后油品性能及nH/nC的变化来判断不同温度条件下MoS2对生物质油轻质油的催化加氢效果。结果表明,随着反应温度的升高,改性油产率逐渐降低,150℃下所得改性油产率为80.3%,而350℃下产率仅为65.4%,但此时的改性油具有较高的nH/nC(3.80),150/350℃两段式反应条件在脱氧方面更具优势。催化加氢机理归结为化合物中含有的不饱和化学键(CC和CO)容易在MoS2催化剂条件下发生加氢或加氢脱氧反应。

英文摘要:

The crude biomass oil obtained from rice husks was a complicated mixture with the unstable physic-chemical properties. Only these biomass oils, which were modified, can be used in diesel engine. The refined biomass oil was prepared by the vacuum distillation approach from the crude biomass oil. The refined biomass-oil was upgraded via the catalytic hydrodeoxygenation over MoS2 under different temperatures (150, 250, 350 and 150/350℃) and 2 MPa. The yields of upgraded oils were calculated, and the properties and nil~no of oils were also analyzed, which were used to evaluate the upgrading performance. The experimental results showed that the yield of upgraded oil decreased with the temperature rising. The yield of upgraded oil was 80.3% at 150℃, while at 350℃, the yield (65.4%) was lower, but the rate of n./nc(3.8) was higher. The two- stage reaction at 150/350℃ turned out the better catalytic deoxygenation than those of the one-stage temperature condition. The catalytic hydrodeoxgenation mechanism over MoS2could be clarified via the unsaturated functional bonds (C=C and C =O sites) of the components in the refined oil that were easily attacked by the hydrogen during the proper temperature and pressure.

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期刊信息
  • 《摩擦学学报》
  • 北大核心期刊(2011版)
  • 主管单位:中国科学院
  • 主办单位:中国科学院兰州化学物理研究所
  • 主编:薛群基
  • 地址:兰州市天水中路18号
  • 邮编:730000
  • 邮箱:tribology@lzb.ac.cn
  • 电话:0931-4968238
  • 国际标准刊号:ISSN:1004-0595
  • 国内统一刊号:ISSN:62-1095/O4
  • 邮发代号:54-42
  • 获奖情况:
  • 中国科学院优秀期刊三等奖,甘肃省达标期刊优秀奖,1999年、2000年连续2年获工程类学术影响因子第一名
  • 国内外数据库收录:
  • 美国化学文摘(网络版),荷兰文摘与引文数据库,美国工程索引,日本日本科学技术振兴机构数据库,中国中国科技核心期刊,中国北大核心期刊(2004版),中国北大核心期刊(2008版),中国北大核心期刊(2011版),中国北大核心期刊(2014版),中国北大核心期刊(2000版)
  • 被引量:11879