中文摘要：

合成和表征了大环过渡金属配合物NiL（L：高氯酸-5，7，7，12，14，14一六甲基-1，4，8，11-四氮杂环十四烷）。配合物NiL与表面活性剂组成的金属胶束作为模拟水解金属酶用于催化BNPP水解。提出了BNPP催化水解的机理；建立了用于计算动力学常数的动力学模型；计算了相关的动力学和热力学常数。结果表明，这种金属胶束表现出较高的催化活性；BNPP催化水解反应是分子内亲核取代反应；所提出的机理和建立的动力学模型是合理的。

英文摘要：

A macro-cychc transitional metal complex NiL （ L： 5,7,7,12, 14, 14-hexamethyl-1,4,8,11 tetraaza-cyclotetradecane perchlorie acid） was synthesized and characterized. The metallomicelle made up of macro-cyclic divalent metal complex and surfactant, as mimic hydrolytic metalloenzyme,was used in BNPP catalytic hydrolysis. The mechanism of BNPP catalytic hydrolysis was proposed. A correlative kinetic model was established, and corresponding thermodynamic and kinetic constants were calculated. The results show that the metallomicelle display higher catalytic activity and the course of the BNPP catalytic reaction is an intramolecular nucleophilic substituent reaction. The mechanism and kinetic model proposed in file paper should be reasonable.