在水冷铜坩埚中采用铜模吸铸法制备出直径中8mm的(zr0.55A10.10Ni0.05cuo.30)100-xNb,(x=0,2,4,6,8,10)合金试样,利用X射线衍射(XRD)、差热分析(DSC)、扫描电镜(SEM)以及准静态压缩试验方法研究了Nb含量对zr55cu30NisAllo块体金属玻璃的非晶形成能力、热稳定性、力学性能和组织的影响。研究结果表明,添加适量的Nb元素能提高zr55cu30Ni5A110合金的热稳定性和非晶形成能力。当Nb含量为g=8时,合金具有最宽的过冷液相区(△L=86K)和最大的非晶形成能力(参数y=t/(Tg+T1)=0.416)。对于Zr55Cu30Ni5A110合金,优化Nb元素掺杂量可以获得最佳的非晶形成能力和热稳定性。Nb的适量添加也有利于提高Zr55Cu30Ni5A110块体金属玻璃的压缩断裂强度和塑性变形能力,其中x=8时,合金的压缩断裂强度和塑性应变量分别达到1877MPa和1.92%,并具有加工硬化现象。
The alloy rods with 3 mm in diameter of ( Zr0. 55 Al0. to Ni0.o5 Cu0. 3o ) 10o-x Nb, (x = 0, 2, 4, 6, 8, 10) were prepared by cop- per mold with suction casting method in water cooling copper crucible. The effect of Nb contents on thermal stability, glass forming a- bility, mechanical properties and microstructures of ( Zr0. 55 Al0. 10Ni0. 05 Cu0. 30) 100 - x Nbx ( x = 0, 2, 4, 6, 8, 10) bulk metallic glass were investigated by utilizing XRD, DSC, SEM and quasi-static compression method. It showed that appropriate Nb addition content could enhance thermal stability, glass forming ability and mechanical properties of the alloys. For ZrssCu3oNisAllo ahoy, the best forming a- bility and thermal stability of bulk metallic glass needed to optimize Nb element doping. The bulk metallic glass with x = 8 exhibited large supercooled liquid region ( AT= = 86 K), compressive strength ( 1877 MPa) and the compressive plasticity( 1.92% ). Also work-hardening of the alloy was revealed.