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Acid/Alkali Gated Photochromism of Diarylethenes with Quinoline Derivatives
  • ISSN号:1001-604X
  • 期刊名称:《中国化学:英文版》
  • 分类:O626.323[理学—有机化学;理学—化学] O626[理学—有机化学;理学—化学]
  • 作者机构:[1]College of Chemistry and Chemical Engineering, Graduate University of Chinese Academy of Sciences, Beijing 100049, China, [2]The Key Lab of Organic Photoelectrons & Molecular Engineering of Ministry of Education, Department of Chemistry, Tsinghua University, Beijing 100084, China
  • 相关基金:Supporting information for this article is available on the WWW under http://dx.doi.org1l 0.1002/cjoc.201200128 Ackowlegement This work was supported by the National Basic Research Program of China (973 Program) with No. 2011 CB706900, National Natural Science Foundation of China with No. 50872149 and No. 50502003, Scientific Research Foundation for Returned Scholars within the Ministry of Education of China, and the President Foundation of the Graduate University of Chinese Academy of Sciences.
中文摘要:

13 与喹啉衍生物相结合的三新 diarylethenes 被综合了。通过 deprotonation/protonation 的控制化学状况,他们在氯仿答案在 UV/Vis 轻照耀下面介绍了一些新不可逆的对光反应变色现象。它在中立氯仿答案在 UV/Vis 轻照耀之上被发现 13 有的井 photoisomerization。到 13 的戒指洞异构体的溶液的酸的增加生产了 1oa3oa,它在 UV/Vis 轻照耀下面执行了可逆对光反应变色行为并且在与增加吊楔底抵销下面逆行回到 13。然而,到 13 的戒指洞异构体的中立 soluton 的底的 addtion 生产了 1ob3ob,它不能在紫外轻照耀下面把关上戒指的异构体改变到 deprotonated。

英文摘要:

Three new diarylethenes 1--3 combined with quinoline derivatives have been synthesized. Through controlled chemical condition of deprotonation/protonation, they presented some new irreversible photochromic phenomenons under UV/Vis light irradiation in chloroform solution. It was found that 1--3 had well photoisomerization upon UV/Vis light irradiation in neutral chloroform solution. Addition of acid to the solution of the ring-opening isomers of 1--3 produced 1 oa--3oa, which performed reversible photochromic behavior under UV/Vis light irradiation and reversed back to 1--3 under neutralizing with adding lewis base. However, addtion of base to neutral soluton of the ring-opening isomers of 1--3 produced lob--3ob, which could not change to the deprotonated ring-closing isomers under UV light irradiation.

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期刊信息
  • 《中国化学:英文版》
  • 主管单位:
  • 主办单位:中国化学会
  • 主编:
  • 地址:上海市枫林路354号中科院上海有机化学研究所
  • 邮编:200032
  • 邮箱:
  • 电话:021-54925243
  • 国际标准刊号:ISSN:1001-604X
  • 国内统一刊号:ISSN:31-1547/O6
  • 邮发代号:4-646
  • 获奖情况:
  • 中国期刊方阵“双高”期刊
  • 国内外数据库收录:
  • 美国化学文摘(网络版),荷兰文摘与引文数据库,美国科学引文索引(扩展库),日本日本科学技术振兴机构数据库,英国英国皇家化学学会文摘
  • 被引量:175