中文摘要：

以壳聚糖为原料，将其与N-（2-氨乙基）-3-氨内基三乙氧基硅烷（AAPTS）反应制得胺苯功能化的壳聚糖（CS—AAPTS），然后将CS—AAPTS与CuBr进行络合制备得到负载型催化剂（CS—CuBr）．通过FT—IR，TGA，XRD以及EDX等分析方法对CS—CuBr催化剂进行表征．结合微波辐射技术以及“一锅法”合成策略，以CS—CuBr为催化剂催化有机炔、卤代烷以及NaN3之间的环加成反应制备l，2，3-三唑．结果表明，CS—CuBr只有良好的催化性能，微波辐射功率为480W，温度为70℃条件下，可快速合成出1,2，3-三唑类化合物．CS—CuBr易回收和重复使用，重复使用4次后仍可保持良好收率．初步放大实验表明，1，2，3．兰唑类化合物能够以94％的收率以十数克规模制备．

英文摘要：

N-（2-Aminoethyl）-3-aminopropyltriethoxysilane-modified chitosan （CS-AAPTS） was successfully prepared by simply refluxing the corresponding CS and AAPTS in toluene solution. Subsequently, CS-AAPTS bound CuBr （CS-CuBr） was synthesized by the reaction of CS-AAPTS with CuBr in DMF at room temperature under N2 atmosphere. The obtained catalyst was characterized by FT-IR, TGA, XRD and EDX. The catalytic performances were evaluated in one-pot multicom- ponent copper-catalyzed azide-alkyne cycloaddition （CuAAC） reaction under microwave-assisted condition. CS-CuBr was found to exhibit obvious catalytic activity to rapidly prepare 1,2,3-triazole compounds under the microwave irradiation power of 480 W and 70℃ operating conditions. Furthermore, the catalyst could be easily recovered by simple filtration and recycled at least 4 cycles without significant loss of activity, and the preparation of 1,2,3-triazoles could be scaled up to multiole-gram conveniently with a yield uo to 94%.