新 sequiterpenoid 化合物 8a-hydroxy-1-isopropyl-4,7-dimethyl-1,2,3,4,6,8a-hexahydro-naphthalene-2,6-dione ( 1 )和七已知的混合物 anti-HH-dimer-coumarin ( 2 ),(?) -5-exo-hydroxy-borneol ( 3 ),O氢氧根苯乙烯的酸( 4 ), 9-hydroxy-ageraphorone ( 5 ), 10H-9-oxo-ageraphorone ( 6 ), 10H-9-oxo-ageraphorone ( 7 )和 9-oxo-10,11-dehydroageraphorone 8 ,从 Eupatorium adenophorum Spreng 的叶子被孤立。结构被红外, 1H 和 13C 阐明 NMR, EIMS, HMBC 和单个水晶的 X 光检查光谱数据。
A new sequiterpenoid compound 8aa-hydroxy-l-isopropyl-4,7-dimethyl-l,2,3,4,6,8a-hexahydro-naphthalene-2,6- dione (1), together with seven known compounds anti-HH-dimer-coumarin (2), (-)-5-exo-hydroxy-borneol (3), O-hydroxyl cinnamic acid (4), 9β-hydroxy-ageraphorone (5), 10Hα-9-oxo-ageraphorone (6), 10Hβ-9-oxo- ageraphorone (7) and 9-oxo-10,11-dehydroageraphorone 8, was isolated from the leaves of Eupatorium adenopho- rum Spreng. The structures were elucidated by IR, ^1H and ^13C NMR, EIMS, HMBC and single-crystal X-ray spectral data.