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A new Sequiterpenoid from Eupatorium adenophorum Spreng
  • ISSN号:1001-604X
  • 期刊名称:《中国化学:英文版》
  • 时间:0
  • 分类:R284.2[医药卫生—中药学;医药卫生—中医学]
  • 作者机构:[1]Department of Chemistry, Beijing Normal University, Beijing 100875, China, [2]Institute of Plant Protection, Chinese Academy of Agricultural Sciences, Beijing 100094, China, [3]Institute ofMateria Medica, Chinese Academy of Medical Sciences and Peking Union Medical College, Beijing 100050, China
  • 相关基金:Project supported by National Natural Science Foundation of China (No. 20372010), Trans-Century Training Program Foundation for the Talents, Ministry of Education of China and Important technical research in agricultural structure regulation of agricultural department (No. 2003-11-04A).
中文摘要:

新 sequiterpenoid 化合物 8a-hydroxy-1-isopropyl-4,7-dimethyl-1,2,3,4,6,8a-hexahydro-naphthalene-2,6-dione ( 1 )和七已知的混合物 anti-HH-dimer-coumarin ( 2 ),(?) -5-exo-hydroxy-borneol ( 3 ),O氢氧根苯乙烯的酸( 4 ), 9-hydroxy-ageraphorone ( 5 ), 10H-9-oxo-ageraphorone ( 6 ), 10H-9-oxo-ageraphorone ( 7 )和 9-oxo-10,11-dehydroageraphorone 8 ,从 Eupatorium adenophorum Spreng 的叶子被孤立。结构被红外, 1H 和 13C 阐明 NMR, EIMS, HMBC 和单个水晶的 X 光检查光谱数据。

英文摘要:

A new sequiterpenoid compound 8aa-hydroxy-l-isopropyl-4,7-dimethyl-l,2,3,4,6,8a-hexahydro-naphthalene-2,6- dione (1), together with seven known compounds anti-HH-dimer-coumarin (2), (-)-5-exo-hydroxy-borneol (3), O-hydroxyl cinnamic acid (4), 9β-hydroxy-ageraphorone (5), 10Hα-9-oxo-ageraphorone (6), 10Hβ-9-oxo- ageraphorone (7) and 9-oxo-10,11-dehydroageraphorone 8, was isolated from the leaves of Eupatorium adenopho- rum Spreng. The structures were elucidated by IR, ^1H and ^13C NMR, EIMS, HMBC and single-crystal X-ray spectral data.

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期刊信息
  • 《中国化学:英文版》
  • 主管单位:
  • 主办单位:中国化学会
  • 主编:
  • 地址:上海市枫林路354号中科院上海有机化学研究所
  • 邮编:200032
  • 邮箱:
  • 电话:021-54925243
  • 国际标准刊号:ISSN:1001-604X
  • 国内统一刊号:ISSN:31-1547/O6
  • 邮发代号:4-646
  • 获奖情况:
  • 中国期刊方阵“双高”期刊
  • 国内外数据库收录:
  • 美国化学文摘(网络版),荷兰文摘与引文数据库,美国科学引文索引(扩展库),日本日本科学技术振兴机构数据库,英国英国皇家化学学会文摘
  • 被引量:175