位置:成果数据库 > 期刊 > 期刊详情页
添加丙二醇生物油存储过程红外光谱及GC—MS分析
  • ISSN号:1671-5292
  • 期刊名称:《可再生能源》
  • 时间:0
  • 分类:TK6[动力工程及工程热物理—生物能] S216.4[农业科学—农业机械化工程;农业科学—农业工程]
  • 作者机构:[1]上海交通大学农业与生物学院生物质能工程研究中心,上海200240
  • 相关基金:国家自然科学基金资助项目(51176121);“十二五”国家科技支撑计划课题资助(2011BAD22B07).
中文摘要:

将不同质量分数(1%,6%,11%,16%和21%)的丙二醇添加到生物油中.对各组生物油存储过程中的理化指标、红外光谱及气相色谱质谱联用进行分析。理化指标结果表明,随着丙二醇质量分数的增大,各丙二醇组生物油最终pH值比空白组分别提高1.64%,3.93%,5.90%,8.85%和12.13%;最终含水率分别降低9.37%,18.80%,23.72%,27.18%和31.51%;最终运动黏度分别降低7.95%,24.27%,37.56%。45.46%和49-87%。红外光谱结果表明,生物油中醇类、酚类以及醛或酮的含量较高,添加丙二醇会影响生物油内部成分和结构。气相色谱质谱联用分析表明,添加丙二醇生物油内部分化合物种类及含量发生了改变,有机酸含量下降。

英文摘要:

Abstruct: Propylene glycol of different mass fractions (1%, 6%, 11%, 16% and 21%) were added to the bio-oil. The physical and chemical indexes, FTIR and GC-MS of each group during stored procedure were investigated. The physical and chemical indexes showed that with the increasing mass fraction of propylene glycol, the final pH value was improved 1.64%,3.93%,5.90%,8.85% and 12.13%, the final water content was decreased 9.37%, 18.80%,23.72%,27.18% and 31.51% and the final kinematic viscosity was decreased 7.95% ,24.27% ,37.56% ,45.46% and 49.87% contrast blank group, respectively. FFIR illustrated that the contents of alcohols, phenols, aldehyde and ketone in bio-oil were higher, the composition and structure of the bio-oil would be influenced by the propylene glycol. GC-MS indicated that the variety and content of parts of the compounds were changed by the propylene glycol. It also manifested that some organic acids were decreased. Key words: bio-oil; propylene glycol ; infrared spectrum; GC-MS

同期刊论文项目
同项目期刊论文
期刊信息
  • 《可再生能源》
  • 中国科技核心期刊
  • 主管单位:辽宁省科学技术厅
  • 主办单位:辽宁省能源研究所
  • 主编:张大雷
  • 地址:辽宁省营口市西市区银泉街65号
  • 邮编:115003
  • 邮箱:kzsny2007@163.com
  • 电话:0417-2832895 2835349
  • 国际标准刊号:ISSN:1671-5292
  • 国内统一刊号:ISSN:21-1469/TK
  • 邮发代号:
  • 获奖情况:
  • 1999-2000年度辽宁省一级期刊
  • 国内外数据库收录:
  • 美国化学文摘(网络版),英国农业与生物科学研究中心文摘,波兰哥白尼索引,美国剑桥科学文摘,中国中国科技核心期刊,中国北大核心期刊(2008版),中国北大核心期刊(2011版),中国北大核心期刊(2014版)
  • 被引量:10629