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α-FeO(OH)纳米棒的制备、表征及光催化性能
  • 期刊名称:材料导报
  • 时间:0
  • 页码:88-90+94
  • 语言:中文
  • 分类:TQ138.1[化学工程—无机化工]
  • 作者机构:[1]中国科学院上海应用物理研究所,上海201800, [2]中国科学院研究生院,北京100049
  • 相关基金:国家自然科学基金(10805069;10875163)
  • 相关项目:碘-125标记特异形貌磁纳米粒生物学行为研究
中文摘要:

通过氧化-沉淀法合成了具有光催化活性的α-FeO(OH)纳米棒,用TGA、SEM、BET等分析方法进行结构表征和性能测试,并对其降解偶氮类染料的性能进行了研究。结果表明,产物主要成分为针铁矿α-FeO(OH),另含有少量Fe3O4;产物长径比较高,比表面积为32.89m2/g,并具有优良的磁性能。在作为光催化剂降解偶氮类染料甲基橙的实验中,α-Fe0(0H)纳米棒表现出较好的催化效果。在21W、50W模拟光源和自然光照下降解3h以上,其脱色率分别为29.8%、43.5%o和76.4%。

英文摘要:

α-FeO(OH) nanorods were prepared by oxidation-precipitation process, and characterized by TGA, SEM, BET, etc. The photocatalytic properties of α-FeO(OH) nanorod were also tested. The results show that the main composition of product is qoethite(α-FeO(OH)), with a little FeaO4 mixed in. The nanorods have a greater length-diameter ratio, good magnetic property, and the specific surface area is 32. 89m2/g. The degradation experi- ments indicate that α-FeO(OH) nanorods have effective photocatalytic activity. The decolouring rates of methyl orange solution are 29.8%, 43.5% and 76. 4% after more than 3 hours' irradiation under 21W, 50W xenon lamp, and natural lighting.

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