采用APS-2A型降水降尘自动采集仪,定位收集2012年5—10月重庆缙云山自然保护站的湿沉降数据,分析该地区大气氮湿沉降浓度及沉降的组成、月变化及季节变化。结果表明:1)相对于NO;.N和DON(可溶性有机氮),降雨中NH4±一N的质量浓度较高,说明该地区NH,的排放量较高;2)缙云山地区大气活性氮主要是还原态的NH4一N,其主要来源于农业生产;3)监测期内湿沉降中NO3--N、NH4±-N和DON的平均质量浓度分别为(0.441±0.304)、(0.821±0.480)和(0.203±0.211)mg/L,3种形态氮的月平均质量浓度排序为NH4±-N〉NO;.N〉DON;4)NOx-N、NHf-N和DON的最大沉降量均出现在5月,其平均湿沉降量分别为(0.642±0.292)、(1.273±0.739)和(0.329±0.231)kg/hm2,占总氮湿沉降量的比例分别是29.76%、56.27%和13.98%;5)氮质量浓度与降雨量、降雨强度之间的相关关系均很弱,而氮湿沉降量与降雨量之间呈显著的线性相关关系(P〈0.01),说明该地区氮湿沉降量主要受降雨量的影响,但是降雨量、降雨强度对氮质量浓度的影响都很小。
Field observation of nitrogen wet deposition in Jinyun Mountain, the natural conservation station of southwestern China, was fixed collected by APS-2A precipitation-dust automatic acquisition instrument from May to October 2012, based on which the composition, monthly and seasonal variation of nitrogen wet deposition were analyzed. Results showed that : 1 ) the concentration of NH4 -N was higher than that of NO3--N and DON (dissolved organic nitrogen) , indicating that emission load of NH3 within this area was generally high; 2) the major form of atmospheric reactive nitrogen in Jinyun Mountain area was reduced nitrogen NH4-N, which primarily came from agricultural productivity; 3 ) the average concentrations of NO3-N, NH4 -N and DON in precipitation were (0. 441 ± 0. 304 ), (0. 821 ± 0. 480 ) and (0. 203± 0. 211 ) mg/L during the monitoring period, respectively, of which the above three nitrogen forms ranked in NH4 -N 〉 NO3- -N 〉 DON ; 4) the highest concentrations of NO3- -N, NH4 -N and DON all occurred in May, and the average values were (0.642 ±0.292), (1.273±0.739) and (0.329± 0. 231) kg/hm2, accounted for 29.76%, 56.27% and 13.98% of the total nitrogen wet deposition, respectively; 5) nitrogen concentration was weakly correlated with rainfall and rainfall intensity, while the total nitrogen wet deposition presented an obvious linear correlation with the precipitation amount (P 〈 0.01 ) , which demonstrates that nitrogen wet deposition is mainly affected by rainfall, but rainfall and rainfall intensity have little impact on N concentration.