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Recent progresses of late-transition metal complexes with nonsymmetric diimine ligands in ethylene polymerization and oligomerization
  • ISSN号:1008-0511
  • 期刊名称:《化工科技》
  • 时间:0
  • 分类:O641.4[理学—物理化学;理学—化学] TQ325.12[化学工程—合成树脂塑料工业]
  • 作者机构:[1]Provincial Key Laboratory of Oil & Gas Chemical Technology, College of Chemistry and Chemical Engineering, Northeast Petroleum University, Daqing 163318, China
  • 相关基金:This work was supported by the National Natural Science Foundation of China (20972025, U1362110), the China National Petroleum Corporation (CNPC) Innovation Foundation (2013D-5006-0503), the Scientific Research Foundation for the Returned Overseas Chinese Scholars, Heilongjiang Province (41417837-8-08016), and the Scientific Research Foundation for Overseas Chinese Scholars, Department of Education of Heilongjiang Province (1154H14).
中文摘要:

为乙烯聚合和 oligomerization 的迟了转变的金属建筑群的研究在最后二十年吸引了很多注意。有对称的 diimine ligands 的很多迟了转变的金属建筑群广泛地被学习了。尽管 unsymmetric diimine 的研究迟了转变的金属建筑群仍然在起始的阶段,一些优异表演在石蜡聚合被观察。在迟了转变的金属建筑群与 unsymmetric diimine ligands 催化的乙烯聚合和 oligomerization 的研究的最近的开发在这评论被总结,与分析的催化剂的催化性能上的复杂结构的影响。

英文摘要:

Researches of late-transition metal complexes for ethylene polymerization and oligomerization have attracted a lot of attention in the last two decades. A large number of late-transition metal complexes with symmetric diimine ligands have been extensively studied. Although the research of unsymmetric diimine late-transition metal complexes was still in the initial stage, some superior performances were observed in olefin polymerization. Recent developments in the research of ethylene poly- merization and oligomerization catalyzed by late-transition metal complexes with unsymmetric diimine ligands were summarized in this review, with the influence of complex structure on the catalytic performance of the catalyst analyzed.

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期刊信息
  • 《化工科技》
  • 中国科技核心期刊
  • 主管单位:中国石油天然气集团公司
  • 主办单位:中国石油天然气股份有限公司吉林石化分公司
  • 主编:鲁建春
  • 地址:吉林市遵义东路27号
  • 邮编:132021
  • 邮箱:zhls3004@sina.com
  • 电话:0432-63995190
  • 国际标准刊号:ISSN:1008-0511
  • 国内统一刊号:ISSN:22-1268/TQ
  • 邮发代号:12-113
  • 获奖情况:
  • 全国石油和化工行业优秀期刊一等奖
  • 国内外数据库收录:
  • 美国化学文摘(网络版),中国中国科技核心期刊
  • 被引量:5069