含溴原子的环钯化合物[PdCl{[(η5-C5H5)]Fe[(η5-C5H3)-NC5H3-Bd}(C3N2H2)(C6H]-2C3H7)2]}(化合物1)与聚乙二醇(PEG)-10000反应,合成出聚乙二醇负载氮杂环卡宾环钯化合物1-PEG(10000).用红外光谱和核磁共振对其结构进行表征.以水为溶剂,K3PO。为碱,1-PEG(10000)能高效催化各种氯代芳烃的Suzuki偶联反应,该催化体系循环使用3次,还能保持较高的催化活性.
Polyethylene glycol-supported N-heterocyclic carbene palladium complex [ 1 -PEG(10000) ] have been prepared from [PdCl{[(η5-C5H5)]Fe[(η5-C5H3)-NC5H3-Bd}(C3N2H2)(C6H]-2C3H7)2]}1 and PEG- 10000. The compound has been characterized by infrared spectroscopy and 1H NMR. Using 1 -PEG(10000) as catalyst in the presence of K3PO4 as base in water at 100℃ provided coupling products in excellent yields. Moreo- ver, the above system could be recycled and reused three times.